2,3-dihydroxyterephthalaldehyde O,O-di(2-(((2-mercaptobenzylidene)amino)oxy)ethyl) dioxime | 1239336-85-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯硫酚类
• 英文名称: 2,3-dihydroxyterephthalaldehyde O,O-di(2-(((2-mercaptobenzylidene)amino)oxy)ethyl) dioxime
• CAS: 1239336-85-6
• 化学式: C₂₆H₂₆N₄O₆S₂
• 分子量: 554.648
• InChiKey: YAFQAEHCOOAMLN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.48
• 重原子数：
  38.0
• 可旋转键数：
  14.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  126.82
• 氢给体数：
  4.0
• 氢受体数：
  12.0

反应信息

• 作为产物：
  描述：

  2,3-dihydroxyterephthalaldehyde O,O-di(2-(aminooxy)ethyl) dioxime 、 2-硫代水杨醛 以 二氯甲烷 为溶剂， 反应 3.0h， 以48%的产率得到2,3-dihydroxyterephthalaldehyde O,O-di(2-(((2-mercaptobenzylidene)amino)oxy)ethyl) dioxime
  参考文献：
  名称：

  Synthesis of Ag⁺-Selective Dipalladium(II) Metallohost Based on O-Alkyloxime Bis(N₂SO) Ligands

  摘要：

  Novel bis(N2SO) ligands 2a (= H4L2a) and 2b (= H4L2b) comprising O-alkyloxime, thiophenol, and phenol moieties were synthesized. The complexation of H4L2a and H4L2b with palladium(II) acetate afforded the dinuclear metallohosts [L2aPd2] and [L2bPd2], which have a recognition site consisting of two sulfur and four oxygen donor atoms. The metallohost [L2bPd2] strongly binds Ag+ to give [(L2bPd2)2Ag]+, whereas no detectable interaction between [L2bPd2] and hard metal cations (Na+, Ca2+, Y3+, La3+, and Lu3+) was observed.

  DOI：

  10.1080/10426501003772110