| 464178-02-7

• CAS: 464178-02-7
• 化学式: C₂₄H₂₀B*C₄₅H₄₁N₂P₂Pt
• 分子量: 1186.1
• InChiKey: ZYFFJNIIDSZORC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cis-dichlorobis(triphenylphosphine)platinum(II) 、 四苯硼钠 、 二甲基氢胺 以 四氢呋喃 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  Cationic phenyl and chloro-platinum(II) complexes with cyanamides and cyanoguanidine. X-ray structure of trans-[Pt(Ph)(NCNMe2)(PPh3)2][BPh4]

  摘要：

  The phenyl-platinum(II) organocyanamide trans-[Pt(Ph)(NCNR2)(PPh3)(2)][BPh4] (R = Me la, Et 1b) or cyanoguanidine cis-[Pt(Ph){NCNC(NH2)(2)}(PPh3)(2)][BPh4] (2) complexes have been prepared by treatment of cis-[PtCl,(PPh3)(2)] in THF with NCNR, or NCNC(NH2)(2), respectively, in the presence of Na[BPh4], whereas the cyanoguanidine chloro-complex cis[PtCl{NCNC(NH2)(2)}(PPh3)(2)][BF4] (3) has been obtained by using Tl[BF4] instead of Na[BPh4]. Complex 3 reacts further with cyanoguanidine, in the presence of Na[BPh4], to produce the di(cyanoguanidine) cis-[Pt{NCNC(NH2)(2)}(2)(PPh3)(2)][BPh4](2) complex 5, whereas the amine complex cis-[PtCl(NH2R')(PPh3)(2)][BF4] (R' = CH2C6H4Me-4, 4) is formed on reaction of the former with NH2R' in CH2Cl2. The X-ray structure of la is also reported. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)00746-6