1-(Dimethoxyphosphorylmethyl)-4-iodobenzene | 58358-46-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(Dimethoxyphosphorylmethyl)-4-iodobenzene
• CAS: 58358-46-6
• 化学式: C₉H₁₂IO₃P
• 分子量: 326.071
• InChiKey: ODNRMNLEGVNXTM-UHFFFAOYSA-N

物化性质

• 沸点：
  350.9±25.0 °C(Predicted)
• 密度：
  1.649±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-(Dimethoxyphosphorylmethyl)-4-iodobenzene 在 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 potassium tert-butylate 、 三乙胺 、 三苯基膦 、 potassium hydroxide 作用下， 以 四氢呋喃 、 异丙醇 、 甲苯 为溶剂， 生成 4-[2-(4-ethynylphenyl)ethenyl]-N,N-diphenylaniline
  参考文献：
  名称：

  Electrogenerated Conductive Polymers from Triphenylamine End-Capped Dendrimers

  摘要：

  Electroactive end-capped dendritic macromolecules were designed and synthesized. Their structures contain triphenylamine moieties as part of the core or dendrons. The electrogenerated films produced with these monomers behaved as conductive dendritic polymers that can be reversible charged, both in the core and in the peripheral units. The design of dendrimer structures with the introduction of systematic changes allows to establish relationships between their electro-optical properties with molecular structural parameters. The films of polymeric material hold good electrical conductivity, reversible electrochemical processes and chemical stability. The results indicate that the use of conjugated and rigid structures in dendritic macromolecules is an important factor in order to obtain electropolymeric films. This work provides a model to design starburst dendrimers capable to form electrochemically active polymers with potential applications in electronic and optoelectronic devices.

  DOI：

  10.1021/ma401085q
• 作为产物：
  描述：

  4-碘甲苯 在 N-溴代丁二酰亚胺(NBS) 、 过氧化苯甲酰 作用下， 以 四氯化碳 、 甲苯 为溶剂， 生成 1-(Dimethoxyphosphorylmethyl)-4-iodobenzene
  参考文献：
  名称：

  Electrogenerated Conductive Polymers from Triphenylamine End-Capped Dendrimers

  摘要：

  Electroactive end-capped dendritic macromolecules were designed and synthesized. Their structures contain triphenylamine moieties as part of the core or dendrons. The electrogenerated films produced with these monomers behaved as conductive dendritic polymers that can be reversible charged, both in the core and in the peripheral units. The design of dendrimer structures with the introduction of systematic changes allows to establish relationships between their electro-optical properties with molecular structural parameters. The films of polymeric material hold good electrical conductivity, reversible electrochemical processes and chemical stability. The results indicate that the use of conjugated and rigid structures in dendritic macromolecules is an important factor in order to obtain electropolymeric films. This work provides a model to design starburst dendrimers capable to form electrochemically active polymers with potential applications in electronic and optoelectronic devices.

  DOI：

  10.1021/ma401085q

文献信息

• Efficient and straightforward click synthesis of structurally related dendritic triazoles
  作者：M. I. Mangione、R. A. Spanevello、M. B. Anzardi

  DOI：10.1039/c7ra09558a

  日期：——

  A simple, rapid and efficient copper-catalyzed 1,3-dipolar cycloaddition reaction is described for the synthesis of a novel family of twelve triazolic dendrimers structurally related. The products were the result of the click reaction of three cores and four different azides in tetrahydrofuran applying a homogeneous copper catalysis. The reaction intermediates and products were obtained in very good

  描述了一种简单，快速和有效的铜催化的1,3-偶极环加成反应，用于合成结构上相关的十二种三唑树枝状大分子的新家族。产物是三个核和四种不同叠氮化物在四氢呋喃中应用均相铜催化的点击反应的结果。使用直接和简单的后处理程序，可以非常好至极好的收率获得反应中间体和产物。这个新的化合物家族包含电活性部分，例如咔唑和三苯胺，这可能使它们成为光电子有机材料开发的极佳候选者。
• TEWARI R. S.; KUMARI N.; KENDURKAR P. S., J. CHEM. AND ENG. DATA <JCEA-AX>, 1976, 21, NO 1, 125-131
  作者：TEWARI R. S.、 KUMARI N.、 KENDURKAR P. S.

  DOI：——

  日期：——