pyridine(trimethylamine)(tetra-15-crown-5-phthalocyaninato)ruthenium(II) | 866417-51-8

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: pyridine(trimethylamine)(tetra-15-crown-5-phthalocyaninato)ruthenium(II)
• CAS: 866417-51-8
• 化学式: C₇₂H₈₆N₁₀O₂₀Ru
• 分子量: 1512.6
• InChiKey: YDLPASMOACPQQT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  吡啶 、 4,5,4',5',4'',5'',4''',5'''-tetrakis(1,4,7,10,13-pentaoxatridecamethylene)phthalocyaninateruthenium(II)(carboxyl)(methanol) 、 十二/十四烷基二甲基氧化胺 以 吡啶 、 氯仿 为溶剂， 以38%的产率得到bis(pyridine)(tetra-15-crown-5-phthalocyaninato)ruthenium(II)
  参考文献：
  名称：

  Ruthenium(ii) complexes with tetra-15-crown-5-phthalocyanine: synthesis and spectroscopic investigation

  摘要：

  The ruthenium complexes with tetra-15-crown-5-phthalocyanine and various axial ligands were synthesized and characterized by spectroscopy. A method for the synthesis of bisaxially coordinated ruthenium(II) tetra-15-crown-5-phthalocyaninates with the N-donor ligands (R4Pc)Ru(L-2) (R4Pc2- = [4,5,4',5',4",5",4"',5"'-tetrakis(1,4,7,10,13-pentaoxotridecamethylene)phthalocyaninate-ion], L is trimethylamine (Me3N), pyridine (py), isoquinoline (iqnl), triethylamine (Et3N), pyrazine (pyz)) was developed. The preparation technique involves selective decarbonylation of (R4Pc)Ru(CO)(MeOH) on treatment with Me3NO in excess N-donor solvent.

  DOI：

  10.1023/b:rucb.0000024832.76270.94