4,5,4',5',4'',5'',4''',5'''-tetrakis(1,4,7,10,13-pentaoxatridecamethylene)phthalocyaninateruthenium(II)(carboxyl)(methanol) | 528817-28-9

• 英文名称: 4,5,4',5',4'',5'',4''',5'''-tetrakis(1,4,7,10,13-pentaoxatridecamethylene)phthalocyaninateruthenium(II)(carboxyl)(methanol)
• 英文别名: (methanol)(tetra-15-crown-5-phthalocyaninato)carbonylruthenium(II)；[Ru(II)(4,5,4',5',4'',5'',4''',5'''-tetrakis(1,4,7,10,13-pentaoxatridecamethylene)phthalocyaninate)(CO)(CH3OH)]；tetra-15-crown-5-phthalocyaninateruthenium(II)(CO)(MeOH)；[(tetra-15-crown-5-phthalocyaninate)(CO)Ru(CH3OH)]；[(15-crown-5)4PcRu(CO)(CH3OH)]
• CAS: 528817-28-9
• 化学式: C₆₆H₇₆N₈O₂₂Ru
• 分子量: 1434.44
• InChiKey: UCZFCLIDTJSURG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.62
• 重原子数：
  97.0
• 可旋转键数：
  0.0
• 环数：
  13.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  327.44
• 氢给体数：
  1.0
• 氢受体数：
  28.0

反应信息

• 作为反应物：
  描述：

  4,5,4',5',4'',5'',4''',5'''-tetrakis(1,4,7,10,13-pentaoxatridecamethylene)phthalocyaninateruthenium(II)(carboxyl)(methanol) 、 十二/十四烷基二甲基氧化胺 以 氯仿 为溶剂， 以14%的产率得到bis(trimethylamine)(tetra-15-crown-5-phthalocyaninato)ruthenium(II)
  参考文献：
  名称：

  Ruthenium(ii) complexes with tetra-15-crown-5-phthalocyanine: synthesis and spectroscopic investigation

  摘要：

  The ruthenium complexes with tetra-15-crown-5-phthalocyanine and various axial ligands were synthesized and characterized by spectroscopy. A method for the synthesis of bisaxially coordinated ruthenium(II) tetra-15-crown-5-phthalocyaninates with the N-donor ligands (R4Pc)Ru(L-2) (R4Pc2- = [4,5,4',5',4",5",4"',5"'-tetrakis(1,4,7,10,13-pentaoxotridecamethylene)phthalocyaninate-ion], L is trimethylamine (Me3N), pyridine (py), isoquinoline (iqnl), triethylamine (Et3N), pyrazine (pyz)) was developed. The preparation technique involves selective decarbonylation of (R4Pc)Ru(CO)(MeOH) on treatment with Me3NO in excess N-donor solvent.

  DOI：

  10.1023/b:rucb.0000024832.76270.94
• 作为产物：
  描述：

  甲醇 、 水合三氯化钌 、 1,2-dicyanobenzo-4,5-(15-crown-5) 以 neat (no solvent) 为溶剂， 以10%的产率得到4,5,4',5',4'',5'',4''',5'''-tetrakis(1,4,7,10,13-pentaoxatridecamethylene)phthalocyaninateruthenium(II)(carboxyl)(methanol)
  参考文献：
  名称：

  Enakieva; Gorbunova; Sakharov, Russian Journal of Inorganic Chemistry, 2002, vol. 47, # 12, p. 1815 - 1820

  摘要：

  DOI：

文献信息

• Monolayers and Langmuir-Blodgett films of crown-substituted phthalocyanines
  作者：V. V. Arslanov、Yu. G. Gorbunova、S. L. Selektor、L. S. Sheinina、O. G. Tselykh、Yu. Yu. Enakieva、A. Yu. Tsivadze

  DOI：10.1007/s11172-005-0150-6

  日期：2004.11

  the subphase surface by an angle of 25°. The Langmuir-Blodgett films of the complex were established to have redox peaks. A high electrochemical stability of the Langmuir-Blodgett films and a high electroactivity of phthalocyanine rings were demonstrated. It was shown by impedance spectroscopy that the binding of Na+ and K+ ions by Langmuir-Blodgett films of the (R4Pc)Ru(MeOH)(CO) complex results in

  合成了四-15-冠-5-酞菁配体及其具有轴向CO和MeOH基团的钌配合物。研究了它们的单层膜和 Langmuir-Blodgett 膜的特性。在配体的情况下，形成分子缔合体的单层膜。建立了混合二元单层中配体和硬脂酸的相容性。硬脂酸改善了配体在水表面的分布，并导致形成固定在其基质中的单层缔合体。发现了 Na+ 阳离子对混合单层的缩合效应。钌络合物 (R4Pc)Ru(MeOH)(CO) 形成稳定的真正单层。堆积中的大环平面相对于亚相表面的法线倾斜 25°。复合物的 Langmuir-Blodgett 膜被确定为具有氧化还原峰。证明了 Langmuir-Blodgett 薄膜的高电化学稳定性和酞菁环的高电活性。阻抗谱表明 (R4Pc)Ru(MeOH)(CO) 复合物的 Langmuir-Blodgett 膜结合 Na+ 和 K+ 离子导致中频区域的阻抗值增加 3 和 5次，分别。
• Synthesis and structure of the (R4Pc)Ru(TED)2 complex, where R4Pc2− is the tetra-15-crown-5-phthalocyaninate dianion and TED is triethylenediamine
  作者：Yulia Yu. Enakieva、Yulia G. Gorbunova、Sergey E. Nefedov、Aslan Yu. Tsivadze

  DOI：10.1070/mc2004v014n05abeh001915

  日期：2004.1

  The ruthenium(II) complex (R4Pc)Ru(TED)(2) R4Pc2- is [4,5,4',5',4",5",4''',5'"-tetrakis-(1,4,7,10,13-pentaoxatridecamethylene)phthalocyaninate anion]; TED is triethylenediamine} with a coordinated tetra-15-crown-5-phthalocyaninate dianion and axially arranged triethylenediamine molecules has been synthesised and characterised.