(Z)-2-(1-adamantyl)but-2-enoic acid | 1401199-93-6

• 分子结构分类: 有机化合物
• 英文名称: (Z)-2-(1-adamantyl)but-2-enoic acid
• CAS: 1401199-93-6
• 化学式: C₁₄H₂₀O₂
• 分子量: 220.312
• InChiKey: GAUCINNQERGQRL-SWGQDTFXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-金刚烷乙酸 在 三甲基氯硅烷 、 1-羟基苯并三唑 、 N,N'-二环己基碳二亚胺 、 sodium iodide 、 lithium diisopropyl amide 作用下， 以 四氢呋喃 、 正己烷 、 乙腈 为溶剂， 反应 72.42h， 生成 (Z)-2-(1-adamantyl)but-2-enoic acid
  参考文献：
  名称：

  Adamantyl-β-butyrolactones: synthesis and ring-opening reactions

  摘要：

  2-(1-Adamantyl)-beta-butyrolactones 3a and 3b were synthesized using very common peptide coupling reagents under mild conditions and their ring-opening reactions were then studied. These novel lactones showed pronounced stability and were resistant to cleavage upon acidic water extraction and column chromatographic purification. The adamantane moiety plays an important function in lowering the lactone reactivity by protecting the electrophilic sites on the four membered ring via steric hindrance. However under certain conditions, both O-C(carbonyl) and O-C(alkyl) bond-cleavage ring-opening reactions were observed. Bond-cleavage at physiological temperature makes these novel lactones especially noteworthy. Novel adamantyl-beta-butyrolactones have a potential to act as biomembrane soluble amphiphiles that might exhibit a combination of stability and biological activity with the latter hopefully predominating. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2012.07.102

文献信息

• Phenolic/alicyclic copolymers and photoresists
  申请人：Shipley Company, L.L.C.

  公开号：US20030207200A1

  公开（公告）日：2003-11-06

  The present invention relates to new polymers that contain repeat units of phenol and photoacid-labile esters that contain an alicyclic group, preferably a bulky group that suitably may contain 7 to about 20 carbons, such as an alkyladamantyl, ethylfencyl, tricyclo decanyl, or pinanyl group. Polymers of the invention are useful as a component of chemically-amplified positive-acting resists.

  本发明涉及含有苯酚和光酸解性酯重复单元的新型聚合物，该酯含有脂环族基团，优选为适当含有7至约20个碳的笨重基团，例如烷基金刚烷基、乙基芬烷基、三环癸烷基或蒎烷基。本发明的聚合物可作为化学增强型正向感光胶的组分使用。
• Copolymers having phenol groups and alicyclic groups and photoresist compositions comprising same
  申请人：Shipley Company LLC

  公开号：EP1091250A1

  公开（公告）日：2001-04-11

  The present invention relates to new polymers that contain repeat units of phenol and photoacid-labile esters that contain an alicyclic group, preferably a bulky group that suitably may contain 7 to about 20 carbons, such as an alkyladamantyl, ethylfencyl, tricyclo decanyl, or pinanyl group. Polymers of the invention are useful as a component of chemically-amplified positive-acting resists.

  本发明涉及新的聚合物，其包含苯和光酸不稳定酯重复单元，该酯含有一个脂环族基团，优选为适当含有7至约20个碳的笨重基团，例如烷基金刚烷基、乙基芬基基、三环癸基或脂松油基团。本发明的聚合物可用作化学增强型正向感光胶的组分。
• Photoacid generators and photoresists comprising same
  申请人：Shipley Company, L.L.C.

  公开号：US20030027061A1

  公开（公告）日：2003-02-06

  This invention relates to new photoacid generator compounds and photoresist compositions that comprise such compounds. In particular, the invention relates to photoacid generator compounds that generate an &agr;,&agr;-difluoroalkyl sulfonic acid upon exposure to activating radiation. Positive- and negative-acting chemically amplified resists that contain such PAGs are particularly preferred. The invention also includes methods for synthesis of such PAGs and &agr;,&agr;-difluoroalkyl sulfonic acids

  本发明涉及新型光酸发生器化合物和包含此类化合物的光刻胶组合物。特别是，本发明涉及光酸发生器化合物，该化合物在受到活化辐射时会生成&agr;,&agr;-二氟烷基磺酸。特别优选的是含有这种 PAG 的正作用和负作用化学放大抗蚀剂。本发明还包括合成此类 PAG 和&agr;,&agr;-二氟烷基磺酸的方法
• FLUORINATED POLYMERS USEFUL AS PHOTORESISTS, AND PROCESSES FOR MICROLITHOGRAPHY
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP1551886B1

  公开（公告）日：2008-09-10
• US6492086B1
  申请人：——

  公开号：US6492086B1

  公开（公告）日：2002-12-10