catena-poly[[(2-methyl-1,3-benzothiazole-N)mercury(II)]-di-μ-chloro] | 325459-23-2

• 英文名称: catena-poly[[(2-methyl-1,3-benzothiazole-N)mercury(II)]-di-μ-chloro]
• CAS: 325459-23-2
• 化学式: C₈H₇Cl₂HgNS
• 分子量: 420.712
• InChiKey: PDUIJYCYMCXQKW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-甲基苯并噻唑 、 mercury dichloride 以 甲醇 为溶剂， 以75%的产率得到catena-poly[[(2-methyl-1,3-benzothiazole-N)mercury(II)]-di-μ-chloro]
  参考文献：
  名称：

  catena-Poly[[(2-methyl-1,3-benzothiazole-N)mercury(II)]-di-μ-chloro]

  摘要：

  The reaction of 2-methyl-1,3-benzothiazole (mebta) with mercury(II) chloride in methanol in a 1:1 molar ratio resulted in the formation of single crystals of the title compound, [HgCl2(C8H7NS)](n). The molecules exist as continuous chlorine-bridged chains in which Hg atoms lie in distorted trigonal bipyramidal environments. The equatorial positions are occupied by an N atom from the ligand [2.236 (8) Angstrom] and two Cl atoms [2.428 (3) and 2.459 (3) Angstrom]. The two axial Hg- Cl contacts to two neighbouring molecules [2.874 (3) and 2.964 (3) Angstrom] are significantly shorter than the sum of the respective van der Waals radii, and form close to linear Cl- Hg-Cl sequences [177.80 (7)degrees].

  DOI：

  10.1107/s0108270100013846