bis(4-methoxyphenoxy)(oxo)vanadium(V) chloride | 198079-10-6

• 英文名称: bis(4-methoxyphenoxy)(oxo)vanadium(V) chloride
• CAS: 198079-10-6
• 化学式: C₁₄H₁₄ClO₅V
• 分子量: 348.657
• InChiKey: VPBUWMGRCCKPTG-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(4-methoxyphenoxy)(oxo)vanadium(V) chloride 、 间氨基苯甲腈 以 甲醇 、 苯 为溶剂， 以79%的产率得到
  参考文献：
  名称：

  4-methoxyphenoxo complexes of monooxovanadium(V) and their reactions with cyanoanilines and cyanopyridines

  摘要：

  The new 4-methoxyphenoxomonooxovanadium(V) complexes with-the general formulae [VOCl3-x(OC6H4OMe-4)(x)] (where x = 1 --> 3) have been conveniently synthesized in good yields using VOCl3 and the trimethylsilyl derivative of 4-methoxyphenol, Me3SiOC6H4OMe-4 as reactants in CCl4. The complexes were characterized by chemical analyses, conductively measurements, IR,H-1 NMR, electronic spectra and thermal studies. Coordination compounds of the parent complexes with cyanoanilines and cyanopyridines have been prepared and studied. Tentative stereochemistries are assigned in each case. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00173-3
• 作为产物：
  描述：

  (4-甲氧基苯氧基)-三甲基硅烷 、 三氯一氧化钒 三氯代氧化钒(V) 以 四氯化碳 为溶剂， 以61%的产率得到bis(4-methoxyphenoxy)(oxo)vanadium(V) chloride
  参考文献：
  名称：

  4-methoxyphenoxo complexes of monooxovanadium(V) and their reactions with cyanoanilines and cyanopyridines

  摘要：

  The new 4-methoxyphenoxomonooxovanadium(V) complexes with-the general formulae [VOCl3-x(OC6H4OMe-4)(x)] (where x = 1 --> 3) have been conveniently synthesized in good yields using VOCl3 and the trimethylsilyl derivative of 4-methoxyphenol, Me3SiOC6H4OMe-4 as reactants in CCl4. The complexes were characterized by chemical analyses, conductively measurements, IR,H-1 NMR, electronic spectra and thermal studies. Coordination compounds of the parent complexes with cyanoanilines and cyanopyridines have been prepared and studied. Tentative stereochemistries are assigned in each case. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00173-3