[di(4-amino-pyridine)silver(I)]CF3SO3 | 690269-35-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: [di(4-amino-pyridine)silver(I)]CF3SO3
• CAS: 690269-35-3
• 化学式: CF₃O₃S*C₁₀H₁₂AgN₄
• 分子量: 445.171
• InChiKey: SFQCKUOXUYJGLU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-氨基吡啶 、 silver trifluoromethanesulfonate 以 氨 为溶剂， 以45%的产率得到[di(4-amino-pyridine)silver(I)]CF3SO3
  参考文献：
  名称：

  Synthesis and Characterization of Ag(I) Salts with Pyridine Derivatives

  摘要：

  Four silver( I) complexes with three pyridyl ligands, 3-amino-pyridine (L-1), 2-amino-pyridine (L-2), and 4,4'-bipyridine (L-3) were synthesized and determined by single-crystal X-ray diffraction. The silver( I) ions in the complexes [Ag(L-1)(2)](CF3SO3) ( 1) and [Ag(L-1)(2)] HCO3 center dot 4H(2)O ( 2) adopt a linear geometry and those in [Ag(L-2)(2)(C6H5COO)] ( 3) takes a Y-shape. [Ag(L-3)(CH3COOH)] (n)(NO3)(n) center dot 10H(2)O ( 4) is a polymeric silver( I) complex which consists of four parallel, one-dimensional chains, where there exist two crystallographically different kinds of Ag( I) cations, one is coordinated in a T-shape fashion and the other in a slightly distorted linear geometry.

  DOI：

  10.1081/sim-200035691