[Ag(tris(2-diphenylphosphinoethyl)amine)](SO3CF3) | 1163137-81-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: [Ag(tris(2-diphenylphosphinoethyl)amine)](SO3CF3)
• CAS: 1163137-81-2
• 化学式: C₄₃H₄₂AgF₃NO₃P₃S
• 分子量: 910.662
• InChiKey: QFZVRVJQVHGTCR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ag(tris(2-diphenylphosphinoethyl)amine)](SO3CF3) 以 二甲基亚砜 为溶剂， 生成 银
  参考文献：
  名称：

  The double-helicate terpyridine silver(I) compound [Ag2L2](SO3CF3)2 (L=4′-phenyl-terpyridine) as a building block for di- and mononuclear complexes

  摘要：

  The double-helicate dinuclear silver(I) complex [Ag2L2](SO3CF3)(2) (1) was obtained by reaction of AgSO3CF3 with 4'-phenyl-terpyridine (L). Each Ag+ ion is coordinated by two N-atoms from one of the ligands and by one N-atom of the other ligand, forming an irregular Ag2N6 bi-triangle geometry, with a metallic bond between the two silver ions. Complex 1 reacts with potentially bidentate ligands (L-1), such as 9,10-bis(diphenylphosphino) anthracene (PAnP), 4,4'-dipyridyl or bis(diphenyl phosphino)methane (DPPM), to give the corresponding dinuclear complexes with bridging L-1, [Ag2L2(mu-L-1)](SO3CF3)(2) (L-1 = PAnP 2, 4,4'-dipyridyl 3 or DPPM 4), whereas on reaction with PPh3 forms the mononuclear complex [AgL(PPh3)](SO3CF3) 5. Reaction of 1 with the potentially tridentate ligand tris(2-diphenylphosphinoethyl)amine (NP3) results in complete decomposition of the coordination spheres to form [Ag(NP3)](SO3CF3) 6. Compound 1 shows a strong fluorescence in the solid state with its excitation band at 383.5 nm, the emission band at 535.5 nm and the lifetime of 4.20 ns, but the derived complexes do not show fluorescent properties. The photoluminescence of 1 in various solvents was also studied. The complexes were characterized by H-1 NMR, elemental analysis, IR, MS, UV and single crystal X-ray diffraction. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.01.018
• 作为产物：
  描述：

  [Ag2(4'-phenyl-terpyridine)2](SO3CF3)2 、 三(2-(二苯基膦基)乙基)胺 以 二氯甲烷 、 乙腈 为溶剂， 以80%的产率得到[Ag(tris(2-diphenylphosphinoethyl)amine)](SO3CF3)
  参考文献：
  名称：

  The double-helicate terpyridine silver(I) compound [Ag2L2](SO3CF3)2 (L=4′-phenyl-terpyridine) as a building block for di- and mononuclear complexes

  摘要：

  The double-helicate dinuclear silver(I) complex [Ag2L2](SO3CF3)(2) (1) was obtained by reaction of AgSO3CF3 with 4'-phenyl-terpyridine (L). Each Ag+ ion is coordinated by two N-atoms from one of the ligands and by one N-atom of the other ligand, forming an irregular Ag2N6 bi-triangle geometry, with a metallic bond between the two silver ions. Complex 1 reacts with potentially bidentate ligands (L-1), such as 9,10-bis(diphenylphosphino) anthracene (PAnP), 4,4'-dipyridyl or bis(diphenyl phosphino)methane (DPPM), to give the corresponding dinuclear complexes with bridging L-1, [Ag2L2(mu-L-1)](SO3CF3)(2) (L-1 = PAnP 2, 4,4'-dipyridyl 3 or DPPM 4), whereas on reaction with PPh3 forms the mononuclear complex [AgL(PPh3)](SO3CF3) 5. Reaction of 1 with the potentially tridentate ligand tris(2-diphenylphosphinoethyl)amine (NP3) results in complete decomposition of the coordination spheres to form [Ag(NP3)](SO3CF3) 6. Compound 1 shows a strong fluorescence in the solid state with its excitation band at 383.5 nm, the emission band at 535.5 nm and the lifetime of 4.20 ns, but the derived complexes do not show fluorescent properties. The photoluminescence of 1 in various solvents was also studied. The complexes were characterized by H-1 NMR, elemental analysis, IR, MS, UV and single crystal X-ray diffraction. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.01.018