tetrachlorotris(dimethylphenylphosphine)tungsten(IV) | 47690-18-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetrachlorotris(dimethylphenylphosphine)tungsten(IV)
• 英文别名: WCl4(PMe2Ph)3
• CAS: 47690-18-6
• 化学式: C₂₄H₃₃Cl₄P₃W
• 分子量: 740.109
• InChiKey: KICMRHNIYJFAID-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  8.92
• 重原子数：
  32.0
• 可旋转键数：
  6.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  tetrachlorotris(dimethylphenylphosphine)tungsten(IV) 在 zinc 作用下， 以 四氢呋喃 为溶剂， 以50%的产率得到mer-WCl₃(PMe₂Ph)₃
  参考文献：
  名称：

  Hills, Adrian; Hughes, David L.; Leigh, G. Jeffery, Journal of the Chemical Society, Dalton Transactions

  摘要：

  DOI：
• 作为产物：
  描述：

  mer-WCl₃(PMe₂Ph)₃ 以 not given 为溶剂， 生成 tetrachlorotris(dimethylphenylphosphine)tungsten(IV) 、 WCl4(PMe2Ph)2 、 二甲基苯基磷
  参考文献：
  名称：

  Rothfuss, Helmut; Barry, Jane T.; Huffman, John C., Inorganic Chemistry, 1993, vol. 32, # 21, p. 4573 - 4577

  摘要：

  DOI：

文献信息

• Tungsten and molybdenum phosphine hexahydrides: The first examples of nine coordination among mononuclear molybdenum complexes
  作者：Robert H. Crabtree、Gregory G. Hlatky

  DOI：10.1016/s0022-328x(00)87041-2

  日期：1982.11

  An improved preparation and some reactions of WH6(PMe2Ph)3 are described. This method has been extended to prepare the novel MoH6 (PR3)3 compounds, the first mononuclear nine-coordinate molybdenum complexes.

  描述了WH 6（PMe 2 Ph）3的改进制备方法和一些反应。此方法已扩展为制备新型MoH 6（PR 3）3化合物，这是第一个单核九配位钼络合物。
• Hydrazido(2–)-complexes of tungsten-(<scp>V</scp>) and -(<scp>VI</scp>) and a bis(diazenido)-complex of tungsten(<scp>IV</scp>). X-Ray crystal structure of cis-[WCl₃(NNH₂)(PMe₂Ph)₂]
  作者：Joseph Chatt、Martin E. Fakley、Peter B. Hitchcock、Raymond L. Richards、N. Tûyet Luong-Thi

  DOI：10.1039/dt9820000345

  日期：——

  The hydrazido(2–)–hydride complexes [WX2H(NNH2)(PMe2Ph)3]X (1; X = Cl or Br), [WCI3H(NNH2)(PMe2Ph)2](2), and [WCl3H(NNHPh)(PR3)2](3)(PR3= PMe2Ph, PMePh2, or PPh3) have been prepared by treatment of [WX2(NNH2)(PMe2Ph)3] with HX in tetrahydrofuran and of [WCl4(PR3)2] with PhNHNH(SiMe3) respectively. The complexes (1; X = Cl) and (3; PR3= PMe2Ph) convert into the hydrazido(2-) complexes cis-[WCl3(NNH2)(PMe2Ph)2](4)

  肼基（2-）-氢化物络合物[WX 2 H（NNH 2）（PMe 2 Ph）3 ] X（1; X = Cl或Br），[WCI 3 H（NNH 2）（PMe 2 Ph）2 ] （2）和[WCl 3 H（NNHPh）（PR 3）2 ]（3）（PR 3 = PMe 2 Ph，PMePh 2或PPh 3）已经通过处理[WX 2（NNH 2）（ PMe 2 Ph）3 ]与四氢呋喃中的HX和[WCl 4（PR 3）2分别用PhNHNH（SiMe 3）。配合物（1; X = Cl）和（3; PR 3 = PMe 2 Ph）转化为hydrazido（2-）配合物cis- [WCl 3（NNH 2）（PMe 2 Ph）2 ]（4）和反式-[WCl 3（NNHPh）（PMe 2 Ph）2 ]（5）分别缓慢重结晶。的X（4）的射线结构（空间群晶Pnma，- [R ，其中NH = 0.055）原子已被定位，示出了酰肼基（2-）配体为具有平坦的N-NH
• Preparation of dimolybdenum carbonyl and ditungsten carbonyl complexes containing triple fluoro bridges
  作者：David M. Dawson、Richard A. Henderson、Adrian Hills、David L. Hughes

  DOI：10.1039/dt9920000973

  日期：——

  The reaction of [WH6(PMe2Ph)3] with HBF4.OEt2, under an atmosphere of carbon monoxide, in tetrahydrofuran gives [W(CO)2(PMe2Ph)2}2(mu-F)3]BF4. The X-ray crystal structure of this compound reveals that the geometry about each tungsten atom is best considered as having a basal plane containing three fluorine atoms, (W-F)av 2.12(1) angstrom, with the remaining four ligands (two carbon monoxide and two phosphines) forming a second, parallel plane, in which the two carbon monoxide ligands are mutually trans, (W-C)av 1.949(6) angstrom, as are the two phosphines, (W-P)av 2.457(1) angstrom. The spectroscopic characteristics of [W(CO)2(PMe2Ph)2}2(mu-F)3]+ are discussed and from this the nature of species formed in the reactions of [MoH4(PR3)4] (R3 = Et3 or MePh2) with HBF4.OEt2 under an atmosphere of carbon monoxide can be inferred.
• Crabtree, Robert H.; Hlatky, Gregory G., Inorganic Chemistry, 1984, vol. 23, # 16, p. 2388 - 2390
  作者：Crabtree, Robert H.、Hlatky, Gregory G.

  DOI：——

  日期：——
• Burrow; Lough; Richards, Inorganica Chimica Acta, 1997, vol. 259, # 1-2, p. 125 - 135
  作者：Burrow、Lough、Richards、Morris

  DOI：——

  日期：——