(N-[2-(diethylamino)-2-oxoethyl]anilino)-triphenylphosphanium;iodide | 136934-61-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (N-[2-(diethylamino)-2-oxoethyl]anilino)-triphenylphosphanium;iodide
• CAS: 136934-61-7
• 化学式: C₃₀H₃₂N₂OP*I
• 分子量: 594.475
• InChiKey: UAKVIKMSKDGMSU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.27
• 重原子数：
  35
• 可旋转键数：
  9
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  23.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  N,N-diethyl-2-iodoacetamide 、 四苯基氨化膦 在 sodium iodide 作用下， 以 乙腈 为溶剂， 反应 8.0h， 以54%的产率得到(N-[2-(diethylamino)-2-oxoethyl]anilino)-triphenylphosphanium;iodide
  参考文献：
  名称：

  Kabachnik, M. I.; Lobanov, D. I.; Matveeva, A. G., Phosphorus, Sulfur and Silicon and the Related Elements, 1991, vol. 62, # 14, p. 243 - 250

  摘要：

  DOI：

文献信息

• Synthesis and CH-acidity of N,N-disubstituted aminotriphenylphosphonium salts
  作者：M. I. Kabachnik、D. I. Lobanov、A. G. Matveeva、O. E. Kovsheva、M. I. Terekhova、�. S. Petrov、P. V. Petrovskii、E. I. Matrosov

  DOI：10.1007/bf00961243

  日期：1991.7

  Several substituted methylaminotriphenylphosphonium salts (APS) of general formula Ph3PN+(R)CH2R']X- have been synthesized. The CH-acidities of some of the prepared APS have been measured by the indicator method in DMSO, with K+ counterion and 9-phenylfluorene (pK 18.5) as standard, showing a pK range of 14.7-24.8. The acidification effect of Ph3PN+(Ph) ((sigma)CH2- = 0.70) and Ph3PN+(Bu) ((sigma)CH2- = 0.68) groups has been evaluated. The results obtained suggest that there is an effective charge on the nitrogen atom in the APS studied and an increased multiplicity of the N-P bond.
• Kabachnik, M. I.; Lobanov, D. I.; Matveeva, A. G., Phosphorus, Sulfur and Silicon and the Related Elements, 1991, vol. 62, # 14, p. 243 - 250
  作者：Kabachnik, M. I.、Lobanov, D. I.、Matveeva, A. G.、Kovsheva, O. E.、Terekhova, M. I.、et al.

  DOI：——

  日期：——