dichloropalladium;N,N-dimethylformamide;oxolan-2-imine | 172989-57-0

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: dichloropalladium;N,N-dimethylformamide;oxolan-2-imine
• CAS: 172989-57-0
• 化学式: C₇H₁₄Cl₂N₂O₂Pd
• 分子量: 335.526
• InChiKey: LPFZRZCLGWTPHV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  Dichloropalladium;oxolan-2-imine 、 N,N-二甲基甲酰胺 以 N,N-二甲基甲酰胺 为溶剂， 以83%的产率得到dichloropalladium;N,N-dimethylformamide;oxolan-2-imine
  参考文献：
  名称：

  Palladium(II)-Promoted Cyclization Reaction of 4-Hydroxybutyronitrile to 2-Iminotetrahydrofuran. X-ray Structure of cis-[PdCl₂{N(H)CCH₂CH₂CH₂O}- (PPh₃)]·¹/₂CH₂Cl₂

  摘要：

  Reaction of 3-bromo-1-propanol with Et(4)N(CN) in CN(?)2Cl(2) at room temperature gives in high yield 4-hydroxybutyronitrile, HO(CH2)(3)CN (1), which upon reaction with Na2PdCl4 affords [PdCl2{N(H)=CCH2CH2CH2O}(2)] (2), containing two 2-iminotetrahydrofuran ligands derived from intramolecular cyclization of 1. Substitution of one imino ligand for an entering nucleophile L leads to the complexes [PdCl2{N(H)=CCH2CH2CH2O}(L)] (L = PPh(3) (3), py (4), DMF (5)). Similarly, the reaction of 2 with 1 equiv of cis-PH2PCH=CHPPh(2) results in the displacement of the two iminolactone ligands and formation of [PdCl2(Ph(2)PCH=CHPPh(2))]. The ligand 1 and the complexes 2-5 were characterized by analytical and spectroscopic techniques. IR data suggest that 2 and 3 are present as a mixture of cis and trans isomers, while 4 and 5 have a trans stereochemistry. Complex 3 gave crystals of the cis form, as evidenced by an X-ray structural determination.

  DOI：

  10.1021/om950740u