cis-[RuH₂(PMePh₂)₄] | 19624-78-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cis-[RuH₂(PMePh₂)₄]
• CAS: 19624-78-3；23940-61-6
• 化学式: C₅₂H₅₄P₄Ru
• 分子量: 903.966
• InChiKey: ZWXQGIOQKIIFLX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.46
• 重原子数：
  57.0
• 可旋转键数：
  12.0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  cis-[RuH₂(PMePh₂)₄] 、 一氧化碳 以 not given 为溶剂， 生成
  参考文献：
  名称：

  钌和铑的氢化膦配合物的制备及核磁共振光谱。

  摘要：

  DOI：

  10.1021/ic50061a033
• 作为产物：
  描述：

  (η6-1,3,5-cyclooctatriene)(η4-1,5-cyclooctadiene)ruthenium(0) 、 二苯基甲氧基膦 在 H₂ 作用下， 以 四氢呋喃 为溶剂， 生成 cis-[RuH₂(PMePh₂)₄]
  参考文献：
  名称：

  New synthetic route to organophosphorous ruthenium dihydride complexes. X-ray crystal structure of cis-H2Ru(Ph2PCH2CH2PPh2)2·C6H6

  摘要：

  DOI：

  10.1016/s0020-1693(00)95493-8

文献信息

• The dominant steric effect in the synthesis of ammine hydrido- and chlorido-Ru(II)- N , N -dimethylhydrazine and mixed alkyl–aryl phosphine complexes: Novel methyldiazene reduction intermediates
  作者：Frederick P. Malan、Afsar Ali、Eric Singleton、Reinout Meijboom

  DOI：10.1016/j.ica.2015.08.019

  日期：2015.10

  Novel cationic hydrido complexes [RuH(1,5-cod)(NH3)(NH2NMe2)(2)](X) (X = PF6, BPh4) and chloridoammine complexes [RuCl(1,5-cod)(NH3)(2)(NH2NMe2)](X) (X = PF6, BPh4), were isolated from the reaction of the polymeric [RuCl2(1,5-cod)](x) with NH2NMe2. Reaction of the hydrido complexes with the phosphine ligands PMe3, PMe2Ph, P(OMe)(2)Ph resulted in the formation of monohydrido-phosphine complexes, whereas reaction with the bulkier PMePh2 ligand gave dihydrido-phosphine complexes. Similar reactions of the chlorido-ammine complexes with the phosphine ligands PMe3, PMe2Ph, P(OMe)(2)Ph, and PMePh2 all sequentially substituted the NH2NMe2 and the 1,5-cod ligands to give the chlorido-ammine phosphine complexes. All complexes were fully characterised and the single crystal X-ray structures were determined for [RuHP(OMe)(2)Ph}(5)](BPh4), [RuH2(PMePh2)(4)], [Ru(PMe2Ph)(3)}(2)(mu-F)(3)](PF6), fac-[RuCl (NH3) (2)(PMe2Ph)(3)](PF6), and [RuCl(NH3)(PMe2Ph)(4)](PF6). Intramolecular strain between coordinated sigma-donor ligands in the Ru(II)-NH2NMe2 precursor complexes as well as the relative steric bulk of incoming r-donor ligands were found to be chemically directing in the formation of monohydrido-, bishydrido, mono-ammine, and bis-ammine ruthenium(II) complexes. (C) 2015 Elsevier B.V. All rights reserved.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ru: SVol., 157, page 431 - 433
  作者：

  DOI：——

  日期：——
• Naphthoquinodimethane complexes of ruthenium(O)
  作者：Nigel J. Simpson、David J. Cole-Hamilton

  DOI：10.1016/s0277-5387(00)80709-3

  日期：1988.1
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ru: SVol., 190, page 511 - 513
  作者：

  DOI：——

  日期：——