Co(Phmal)(Him)4 | 934748-33-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: Co(Phmal)(Him)4
• 英文别名: Co(phenylmalonate)(imidazole)4
• CAS: 934748-33-1
• 化学式: C₂₁H₂₂CoN₈O₄
• 分子量: 509.45
• InChiKey: GABSZFLIWOOHHJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Co(Phmal)(Him)4 以 neat (no solvent, solid phase) 为溶剂， 生成 cobalt(II) oxide
  参考文献：
  名称：

  Self assembly of a novel mixed-ligand hydrogen bonding three dimensional supramolecular network [Co(Phmal)(Him)4]

  摘要：

  A novel supramolecular mixed ligand complex of formula [Co(Phmal)(Him)(4)] (Phmal = phenylmalonate, Him = imidazole) has been synthesized and characterized by FT-IR spectroscopy, thermogravimetric analysis (TG), UV-Vis spectra. X-ray crystallographic studies of the complex reveal that the cobalt atom exhibits a distorted octahedral geometry being coordinated by four nitrogen atoms of Him ligands, two oxygen atoms from the phenylmalonate ligand. The intramolecular C-H center dot center dot center dot pi interaction exists in the title complex. The three dimensional supramolecular network is constructed from the strong intermolecular N-H center dot center dot center dot O hydrogen bonds. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2006.07.033
• 作为产物：
  描述：

  咪唑 、 cobalt(II) nitrate hexahydrate 、 苯丙二酸 在 NaOH 作用下， 以 甲醇 、 水 为溶剂， 以42%的产率得到Co(Phmal)(Him)4
  参考文献：
  名称：

  Self assembly of a novel mixed-ligand hydrogen bonding three dimensional supramolecular network [Co(Phmal)(Him)4]

  摘要：

  A novel supramolecular mixed ligand complex of formula [Co(Phmal)(Him)(4)] (Phmal = phenylmalonate, Him = imidazole) has been synthesized and characterized by FT-IR spectroscopy, thermogravimetric analysis (TG), UV-Vis spectra. X-ray crystallographic studies of the complex reveal that the cobalt atom exhibits a distorted octahedral geometry being coordinated by four nitrogen atoms of Him ligands, two oxygen atoms from the phenylmalonate ligand. The intramolecular C-H center dot center dot center dot pi interaction exists in the title complex. The three dimensional supramolecular network is constructed from the strong intermolecular N-H center dot center dot center dot O hydrogen bonds. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2006.07.033