methyl bicyclo[3.2.0]hept-6-ene-6-carboxylate | 51326-24-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: methyl bicyclo[3.2.0]hept-6-ene-6-carboxylate
• 英文别名: methyl bicyclo[3.2.0]hepta-6-ene-6-carboxylic acid
• CAS: 51326-24-0
• 化学式: C₉H₁₂O₂
• 分子量: 152.193
• InChiKey: BVCUCMQTHNFCGT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  methyl bicyclo[3.2.0]hept-6-ene-6-carboxylate 、 Grubbs III catalyst 以 二氯甲烷-D2 为溶剂， 生成
  参考文献：
  名称：

  A Bicyclo[4.2.0]octene-Derived Monomer Provides Completely Linear Alternating Copolymers via Alternating Ring-Opening Metathesis Polymerization (AROMP)

  摘要：

  Strained bicyclic carbomethoxy olefins were utilized as substrates in alternating ring-opening metathesis polymerization and found to provide low-dispersity polymers with novel backbones. The polymerization of methyl bicyclo[4.2.0]oct-7-ene-7-carboxylate with cyclohexene in the presence of the fast-initiating Grubbs catalyst (H(2)IMes)(3-Br-Pyr)(2)Cl2Ru=CHPh leads to a completely linear as well as alternating copolymer, as demonstrated by NMR spectroscopy, isotopic labeling, and gel permeation chromatography. In contrast, intramolecular chain-transfer reactions were observed with [5.2.0] and [3.2.0] bicyclic carbomethoxy olefins, although to a lesser extent than with the previously reported monocyclic cyclobutenecarboxylic ester monomers [Song, A.; Parker, K A.; Sampson, N. S. J. Am. Chem. Soc. 2009, 131, 3444]. Inclusion of cyclohexyl rings fused to the copolymer backbone minimizes intramolecular chain-transfer reactions and provides a framework for creating alternating functionality in a one-step polymerization.

  DOI：

  10.1021/ma5012039
• 作为产物：
  描述：

  丙炔酸甲酯 、 环戊烯 在 三氯化铝 作用下， 以 苯 为溶剂， 生成 methyl bicyclo[3.2.0]hept-6-ene-6-carboxylate
  参考文献：
  名称：

  Lewis acid catalyzed reactions of methyl propiolate with unactivated alkenes

  摘要：

  DOI：

  10.1021/ja00512a029

文献信息

• ALKENE ISOMERIZATION AS AN ENTRY TO EFFICIENT ALTERNATING RING-OPEINING METATHESIS POLYMERIZATION (i-AROMP)
  申请人：The Research Foundation for The State University of New York

  公开号：US20180002481A1

  公开（公告）日：2018-01-04

  This invention relates to the field of polymers and olefin polymerization, and more specifically olefin metathesis polymerization. Specifically, the present invention provides a polymer comprising rigorously alternating AB subunits and methods of formation of the AB alternating polymers. In the polymers and process of the invention, the A monomer is derived from a cyclobutene derivative, and the B monomer is derived from a cyclohexene derivative. The polymerization takes place in the presence of an olefin metathesis catalyst.

  这项发明涉及聚合物和烯烃聚合领域，更具体地涉及烯烃交换聚合。具体而言，本发明提供了一种包含严格交替的AB亚基的聚合物以及形成AB交替聚合物的方法。在本发明的聚合物和工艺中，A单体源自环丁烯衍生物，而B单体源自环己烯衍生物。聚合反应在烯烃交换催化剂存在下进行。
• SNIDER B. B.; RODINI D. J.; CONN R. S. E.; SEALFON S., J. AMER. CHEM. SOC., 1979, 101, NO 18, 5283-5293
  作者：SNIDER B. B.、 RODINI D. J.、 CONN R. S. E.、 SEALFON S.

  DOI：——

  日期：——
• 10.1016/0040-4039(96)00038-x
  作者：Jenner, Gerard、Papadopoulos, Mihail

  DOI：10.1016/0040-4039(96)00038-x

  日期：——
• [EN] ALKENE ISOMERIZATION AS AN ENTRY TO EFFICIENT ALTERNATING RING-OPENING METATHESIS POLYMERIZATION (i-AROMP)<br/>[FR] ISOMÉRISATION D'ALCÈNE EN TANT QU'ENTRÉE DANS UNE POLYMÉRISATION PAR OUVERTURE DE CYCLE PAR MÉTATHÈSE (I-AROMP) ALTERNÉE EFFICACE
  申请人：UNIV NEW YORK STATE RES FOUND

  公开号：WO2016154135A1

  公开（公告）日：2016-09-29

  This invention relates to the field of polymers and olefin polymerization, and more specifically olefin metathesis polymerization. Specifically, the present invention provides a polymer comprising rigorously alternating AB subunits and methods of formation of the AB alternating polymers. In the polymers and process of the invention, the A monomer is derived from a cyclobutene derivative, and the B monomer is derived from a cyclohexene derivative. The polymerization takes place in the presence of an olefin metathesis catalyst.