1-ferrocenylethynylanthraquinone | 318498-67-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1-ferrocenylethynylanthraquinone
• 英文别名: Cyclopenta-1,3-diene;1-(2-cyclopenta-1,3-dien-1-ylethynyl)anthracene-9,10-dione;iron(2+)
• CAS: 318498-67-8
• 化学式: C₂₆H₁₆FeO₂
• 分子量: 416.259
• InChiKey: WXIFAXQBQNGURP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.98
• 重原子数：
  29
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-ferrocenylethynylanthraquinone 、 三氟甲磺酸 以 苯甲腈 为溶剂， 生成 η5-cyclopentadienyl-[η6-(9-hydroxy-10-oxo-1,10-dehydro-1-anthrylidenevinylidene)-2,4-cyclopentadiene]iron(II) trifluoromethanesulfonate *0.1CH2Cl2
  参考文献：
  名称：

  Novel Protonation-Induced Structural Conversion of an Ethynylene-Bridged Ferrocene–Anthraquinone Complex

  摘要：

  1-二茂铁乙炔基蒽醌通过质子化发生结构排列，形成富烯-富烯炔结构。

  DOI：

  10.1246/cl.2000.1328
• 作为产物：
  描述：

  二茂铁乙炔 、 1-溴蒽醌 以 not given 为溶剂， 以84%的产率得到1-ferrocenylethynylanthraquinone
  参考文献：
  名称：

  Novel Protonation-Induced Structural Conversion of an Ethynylene-Bridged Ferrocene–Anthraquinone Complex

  摘要：

  1-二茂铁乙炔基蒽醌通过质子化发生结构排列，形成富烯-富烯炔结构。

  DOI：

  10.1246/cl.2000.1328

文献信息

• Counterion-Dependent Valence Tautomerization of Ferrocenyl-Conjugated Pyrylium Salts
  作者：Mio Kondo、Maai Uchikawa、Kosuke Namiki、Wen-Wei Zhang、Shoko Kume、Eiji Nishibori、Hiroyuki Suwa、Shinobu Aoyagi、Makoto Sakata、Masaki Murata、Yoshio Kobayashi、Hiroshi Nishihara

  DOI：10.1021/ja900393e

  日期：2009.9.2

  1-Ferrocenylethynylanthraquinone (1-FcAq), which is a donor (D)-aoceptor (A) conjugated compound consisting of a ferrocene (Fc) acting as a donor, an anthraquinone (Aq) acting as an acceptor, and an ethynyl linker, undergoes a cyclocondensation reaction with strong organic acid, and forms 2-ferrocenyloxodihydrodibenzochromenylium salts ([1-FcPyl]X-+(-) where X = TFSI, TfO, PF6, and BF4). [1-FcPyl](+) were also characterized as conjugated donor-acceptor compounds, and electrochemical properties, UV-vis absorption spectra, single-crystal X-ray analysis, and TD-DFT calculations have indicated that the LUMO level of [1-FcPyl](+) is lower than that of 1-FcAq because of the much larger, pi-conjugated system in [1-FcPyl](+). Variable-temperature Mossbauer spectroscopy (12-300 K) showed that Fe(II) was dominant for the TFSI-, PF6-, and BF4- salts of [1-FcPyl](+); although the Fe(III) species was also observed at all temperature ranges, the molar ratio of Fe(Ill) species increased at higher temperatures in the TFSI- and PF6- salts. This finding indicates that valence tautomerization (VT) between 1-FcPyl(+) and 1-Fc(+)Pyl occurs in the solid state of the TFSI- and the PF6- salts, but not in the BF4- salt. Variable-temperature (3.5-310 K) IR spectroscopy showed that the frequencies of the skeletal vibration of the ferrocene moiety decreased with increasing temperature in the TFSI- and PF6- salts, indicating the development of a ferrocenium-like character. The precision of the bond lengths of the [1-FcPyl](+) moiety (0-003-0.004 angstrom) determined by single-crystal X-ray analysis (113 and 273 K) is not sufficient to demonstrate the effect of the counterion on VT. The dihedral angle between the ferrocene and the pyrylium moieties in the BF4- salt (11.25(15)degrees) is larger than that in the TFSI- (6.63(12)degrees) and PF6- (9.55(15)degrees) salts. Furthermore, the planarity of the acceptor moiety (estimated from the dihedral angle between Ph1 and Ph2) is lower in the BF4- salt compared with that of other salts. These increased dihedral angles might cause a weaker D-A interaction and a destabilization of the acceptor moiety (i.e., raising a LUMO level), leading to lower stability of the Fe(Ill) (1-Fc(+)Pyl) species. Variable-temperature X-ray powder diffraction (VT XRPD, 100-300 K) revealed that the temperature dependence of the Fe-P distance in the PF6- salt was smaller than that of the Fe B distance in the BF4+ salt. Our interpretation of this phenomenon is that the molar ratio of the Fe(III) species is increased in the PF6- salt, and that the Coulombic force between the ferrocene moiety and PF6- anion increases, preventing an increase in the Fe-P distance. This indicates that the electrostatic interaction between the [1-FcPyl](+) moiety and the counteranion may affect the occurrence of VT.
• Protonation-Induced Cyclocondensation of 1-Aryl Ethynylanthraquinones: Expanding the π Conjugation
  作者：Mio Kondo、Maai Uchikawa、Wen-Wei Zhang、Kosuke Namiki、Shoko Kume、Masaki Murata、Yoshio Kobayashi、Hiroshi Nishihara

  DOI：10.1002/anie.200701766

  日期：2007.8.20