{Au2(μ-(diphenylarsino)(diphenylphosphino)ethane)Cl2} | 110456-66-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: {Au2(μ-(diphenylarsino)(diphenylphosphino)ethane)Cl2}
• CAS: 110456-66-1
• 化学式: C₂₆H₂₄AsAu₂Cl₂P
• 分子量: 907.211
• InChiKey: QVVHIDAVXVGOLH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  32
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  {Au2(μ-(diphenylarsino)(diphenylphosphino)ethane)Cl2} 、 potassium 1,1-dicyanoethylene-2,2-ditholate 以 甲醇 、 丙酮 为溶剂， 以68%的产率得到{Au2(μ-1,1-dicyanoethene-2,2-dithiolate)(μ-(diphenylarsino)(diphenylphosphino)ethane)}
  参考文献：
  名称：

  Syntheses of dinuclear gold(I) ring complexes containing 1,1-dicyanoethene-2,2-dithiolate-S, S and bis(diphosphines) as bridging ligands. X-ray crystal structure of [Au2μ-(i-MNT)μ-(dppee)]

  摘要：

  The reaction of [Au2mu-bis(diphosphine)Cl2] with potassium 1,1-dicyanoethene-2,2-dithiolate [K2(i-MNT)], yields the heterobridged complexes: [Au2mu-(i-MNT)mu-(dppee)] (1) (dppee=bis(diphenylphosphinoethylene)), [Au2mu-(i-MNT)mu-(dppe)] (2) (dppe=bis(diphenylphosphino)ethane), [Au2mu-(i-MNT)mu-(dppb)] (3) (dppb = bis(diphenylphosphino)butane), [Au2mu-(i-MNT)mu-(dppAs)] (4) (dppAs = (diphenylarsino)(diphenylphosphino)ethane). The molecular structure of 1 is described. Complex 1 crystallized in the triclinic space group P1BAR with a = 10.451(2), b = 11.774(1), c = 13.432(2) angstrom, alpha = 65.40(1), beta = 82.30(1), gamma = 77.75(1)-degrees and V = 1466.6(4) angstrom3. The structure features two linear two-coordinate gold(I) centers bridged by the i-MNT ligand on one side and by a bis(diphosphine) ligand on the other forming a dinuclear complex with an Au ... Au distance of 2.867(1) angstrom in a twisted nine-membered ring structure.

  DOI：

  10.1016/0020-1693(93)03741-r
• 作为产物：
  描述：

  (tetrahydrothiophene)gold(I) chloride 在 Ph₂P(CH₂)2AsPh₂ 作用下， 以 二氯甲烷 为溶剂， 生成 {Au2(μ-(diphenylarsino)(diphenylphosphino)ethane)Cl2}
  参考文献：
  名称：

  Brown, Scott S. D.; Salter, Ian D.; Dyson, David B., Journal of the Chemical Society, Dalton Transactions, 1988, p. 1795 - 1802

  摘要：

  DOI：

文献信息

• Syntheses of dinuclear gold(I) ring complexes containing 1,1-dicyanoethene-2,2-dithiolate-S, S and bis(diphosphines) as bridging ligands. X-ray crystal structure of [Au2μ-(i-MNT)μ-(dppee)]
  作者：Rosa M. Dávila、Anabel Elduque、Richard J. Staples、Michele Harlass、John P. Fackler

  DOI：10.1016/0020-1693(93)03741-r

  日期：1994.3

  The reaction of [Au2mu-bis(diphosphine)Cl2] with potassium 1,1-dicyanoethene-2,2-dithiolate [K2(i-MNT)], yields the heterobridged complexes: [Au2mu-(i-MNT)mu-(dppee)] (1) (dppee=bis(diphenylphosphinoethylene)), [Au2mu-(i-MNT)mu-(dppe)] (2) (dppe=bis(diphenylphosphino)ethane), [Au2mu-(i-MNT)mu-(dppb)] (3) (dppb = bis(diphenylphosphino)butane), [Au2mu-(i-MNT)mu-(dppAs)] (4) (dppAs = (diphenylarsino)(diphenylphosphino)ethane). The molecular structure of 1 is described. Complex 1 crystallized in the triclinic space group P1BAR with a = 10.451(2), b = 11.774(1), c = 13.432(2) angstrom, alpha = 65.40(1), beta = 82.30(1), gamma = 77.75(1)-degrees and V = 1466.6(4) angstrom3. The structure features two linear two-coordinate gold(I) centers bridged by the i-MNT ligand on one side and by a bis(diphosphine) ligand on the other forming a dinuclear complex with an Au ... Au distance of 2.867(1) angstrom in a twisted nine-membered ring structure.
• Brown, Scott S. D.; Salter, Ian D.; Dyson, David B., Journal of the Chemical Society, Dalton Transactions, 1988, p. 1795 - 1802
  作者：Brown, Scott S. D.、Salter, Ian D.、Dyson, David B.、Parish, R. V. ('Dick')、Bates, Paul A.、Hursthouse, Michael B.

  DOI：——

  日期：——