[(octadecyl-pyridin-2-ylmethyl-amine)2Cu(II)NO3]NO3 | 1046769-47-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [(octadecyl-pyridin-2-ylmethyl-amine)2Cu(II)NO3]NO3
• CAS: 1046769-47-4
• 化学式: C₄₈H₈₈CuN₅O₃*NO₃
• 分子量: 908.809
• InChiKey: TUVJQEQSKKUZJE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper(II) nitrate trihydrate 、 N-octadecyl-pyridin-2-ylmethyl-amine 以 二氯甲烷 为溶剂， 以84%的产率得到[(octadecyl-pyridin-2-ylmethyl-amine)2Cu(II)NO3]NO3
  参考文献：
  名称：

  Influence of the Apical Ligand in the Thermotropic Mesomorphism of Cationic Copper-Based Surfactants

  摘要：

  A new pyridine-based bidentate ligand L-PyC18 was used to develop copper-containing surfactants that exhibit mesomorphism, Complexes [(L-PyC18)(2)(CuY)-Y-II]Y Were synthesized, where Y is an anionic ligand bromo (1), nitrato (2), or perchlorato (3). The nature of these apical ligands determines the mesogenic behavior of 1-3: The smallest bromo-substituted species 1 shows a metastable liquid crystalline phase at 110 degrees C, the nitrato-substituted 2 increases the transition temperature to 136 degrees C, and the bulky perchlorato-substituted 3 shows reversible mesophases at 153 degrees C. The behavior of these complexes shows similarities and suggests that at low temperatures the crystals of these compounds are bilayered structures with interdigitated alkyl tails. At higher temperatures the tails undergo rapid conformational changes that force these layers to swell until the opposing alkyl chains are separated from each other, and the mesophase is a monolayer smectic A. Small changes in the geometry of cationic mesogens can be imposed by the presence of apically coordinated anions, allowing for tuning in the properties of the resulting mesophases.

  DOI：

  10.1021/ic8005162

文献信息

• Cationic Copper(II)-containing Surfactants: Molecular Structures, Film Morphology, and Influence on the Alignment of Nematic Mesogens
  作者：Cláudio N. Verani、Jeffery Driscoll、Paul H. Keyes、Mary Jane Heeg

  DOI：10.1021/ic5004098

  日期：2014.6.2

  mN·m–1 and average areas of ca. 50 Å2. A plateau around 15 mN·m–1 is observed for 3, 4, and 5 and associated with the formation of dendritic domains about 50 μm in size. Species 2 and 6 lack this plateau and show domains of ca. 5 μm. Once transferred onto solid substrates, the resulting Langmuir–Blodgett film of 3 at 18 mN·m–1 influences the alignment of the nematic liquid crystal N-(4-methoxybenzylidene)-4-butylaniline

  我们讨论了阳离子金属表面活性剂[（L Py14）2 Cu II ClO 4 ] ClO 4（1），[（L Py16）2 Cu II ClO 4 ] ClO 4（2），[（L Py18）2 Cu II ClO 4 ] ClO 4（3），[（L Py18）2 Cu II NO 3 ] NO 3（4），[（L Py18）2 Cu II Cl] Cl（5）和[（L Py18）2 Cu II Br] Br（6）通过用铜处理含有四，六或十八烷基链的合适的烷基胺甲基-2-吡啶配体来获得盐。这些金属表面活性剂在红外光谱带，具有同位素模式的光谱质量和元素组成之间显示出极好的一致性。可用于单晶X射线数据1，2，5和先前公布3揭示了在基面上结合到每个烷基胺甲基吡啶配体的胺和吡啶上的三角双锥体铜（II）离子和在顶端位置上结合了阴离子大肠菌素。除了具有最短十四烷基（C 14）链的表面活性剂外，这些物质还产生具有45–55