(+)(CD)563-Λ-trans-O-[Co(ethylenedithiodiacetate)(ethylenediamine)]Cl * H2O | 231608-98-3

• 分子结构分类: 有机化合物
• 英文名称: (+)(CD)563-Λ-trans-O-[Co(ethylenedithiodiacetate)(ethylenediamine)]Cl * H2O
• CAS: 231608-98-3
• 化学式: C₈H₁₆CoN₂O₄S₂*Cl*H₂O
• 分子量: 380.82
• InChiKey: BVWKCPGCDCPHRQ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (+)(CD)563-Λ-trans-O-[Co(ethylenedithiodiacetate)(ethylenediamine)]Cl * H2O 、 sodium perchlorate 以 水 为溶剂， 以91%的产率得到trans(C,O)-[Co(CH2SCH2CH2COO)(ethylenediamine)]ClO4
  参考文献：
  名称：

  Three-Membered −SCoCH₂ Chelate Ring Complex Formed by Photodecarboxylation Reaction of Optically Active trans(O)-[Co(edtda)(en)]Cl (edtda = Ethylenedithiodiacetate)

  摘要：

  A [Co(N)(2)(O)(2)(S)(2)]-type complex containing two coordinated thioether groups, trans(O)-[Co(edtda)(en)](+) (edtda = ethylenedithiodiacetate; en = ethylenediamine), has been prepared which was spontaneously resolved. The photodecarboxylation reaction of the trans(a)-[Co(edtda)(en)](+) provides trans(C,O)-[Co(CH2S(CH2)(2)SCH2COO)(en)](+), which has a -SCoCH2 three-membered ring. The crystal structures, UV/vis absorption, H-1 NMR spectra, and chiral inversion reaction of these complexes are discussed in connection with their stereochemistry.

  DOI：

  10.1021/ic981391+
• 作为产物：
  描述：

  cobalt(II) nitrate hexahydrate 、 1,2-双(羧甲硫基)-乙烷 、 potassium chloride 、 乙二胺 在 KOH 、 PbO₂ 作用下， 以 水 为溶剂， 以51%的产率得到(+)(CD)563-Λ-trans-O-[Co(ethylenedithiodiacetate)(ethylenediamine)]Cl * H2O
  参考文献：
  名称：

  Three-Membered −SCoCH₂ Chelate Ring Complex Formed by Photodecarboxylation Reaction of Optically Active trans(O)-[Co(edtda)(en)]Cl (edtda = Ethylenedithiodiacetate)

  摘要：

  A [Co(N)(2)(O)(2)(S)(2)]-type complex containing two coordinated thioether groups, trans(O)-[Co(edtda)(en)](+) (edtda = ethylenedithiodiacetate; en = ethylenediamine), has been prepared which was spontaneously resolved. The photodecarboxylation reaction of the trans(a)-[Co(edtda)(en)](+) provides trans(C,O)-[Co(CH2S(CH2)(2)SCH2COO)(en)](+), which has a -SCoCH2 three-membered ring. The crystal structures, UV/vis absorption, H-1 NMR spectra, and chiral inversion reaction of these complexes are discussed in connection with their stereochemistry.

  DOI：

  10.1021/ic981391+