| 65058-05-1

• 分子结构分类: 有机化合物
• CAS: 65058-05-1
• 化学式: Cs*H₆O₆Sb
• 分子量: 356.699
• InChiKey: JVSACJRUFIIYGZ-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cesium hydroxide 、 氯化锑(V) 、 水 在 ammonia 作用下， 以 水 为溶剂， 以55%的产率得到
  参考文献：
  名称：

  Synthesis, crystal structure and characterization of alkali metal hydroxoantimonates

  摘要：

  Several alkali metal hydroxoantimonates, K-2[Sb(O)(OH)(5)], Na[Sb(OH)(6)], Cs[Sb(OH)(6)] and Cs-2[Sb-2(mu-O)(2)(OH)(8)] were isolated from aqueous solutions and characterized by single crystal and powder X-ray diffraction studies and by FTIR and thermal analysis. Crystal structures involving [Sb(O)(OH)(5)](2) were never anticipated before, and this is also the first disclosure of a dinuclear antimonate [Sb-2(mu-O)(2)(OH)(8)](2). Aqueous antimonate solutions of different pH were studied by high resolution electrospray mass spectrometry showing pH indifferent spectra and predominance of the mono and dinuclear antimonate species at pH 4-10. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.08.007