4-O-acetyl-6-O-benzoyl-2,3-di-O-methyl-α-D-glucopyranosyl-(1->4)-2-deoxy-3,6-di-O-methyl-α-D-arabino-hexopyranosyl-(1->4)-6-O-benzoyl-2,3-di-O-methyl-α-D-glucopyranosyl-(1->4)-2-deoxy-3,6-di-O-methyl-α-D-arabino-hexopyranosyl-(1->4)-6-O-benzoyl-2,3-di-O-methyl-α-D-glucopyranosyl-(1->4)-1-O-acetyl-2-deoxy-3,6-di-O-methyl-α-D-arabino-hexopyranose | 1119276-09-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 4-O-acetyl-6-O-benzoyl-2,3-di-O-methyl-α-D-glucopyranosyl-(1->4)-2-deoxy-3,6-di-O-methyl-α-D-arabino-hexopyranosyl-(1->4)-6-O-benzoyl-2,3-di-O-methyl-α-D-glucopyranosyl-(1->4)-2-deoxy-3,6-di-O-methyl-α-D-arabino-hexopyranosyl-(1->4)-6-O-benzoyl-2,3-di-O-methyl-α-D-glucopyranosyl-(1->4)-1-O-acetyl-2-deoxy-3,6-di-O-methyl-α-D-arabino-hexopyranose
• CAS: 1119276-09-3
• 化学式: C₇₃H₁₀₂O₃₃
• 分子量: 1507.59
• InChiKey: DLZLVXFRRJAULA-XLEUBWFVSA-N

反应信息

• 作为产物：
  描述：

  、 乙酸酐 在 吡啶 作用下， 反应 12.0h， 生成 4-O-acetyl-6-O-benzoyl-2,3-di-O-methyl-α-D-glucopyranosyl-(1->4)-2-deoxy-3,6-di-O-methyl-α-D-arabino-hexopyranosyl-(1->4)-6-O-benzoyl-2,3-di-O-methyl-α-D-glucopyranosyl-(1->4)-2-deoxy-3,6-di-O-methyl-α-D-arabino-hexopyranosyl-(1->4)-6-O-benzoyl-2,3-di-O-methyl-α-D-glucopyranosyl-(1->4)-1-O-acetyl-2-deoxy-3,6-di-O-methyl-α-D-arabino-hexopyranose
  参考文献：
  名称：

  Synthesis of 2-deoxy cyclic and linear oligosaccharides by oligomerization of monomers

  摘要：

  Cyclic and linear oligosaccharides constituted with 2-deoxy sugar units are synthesized by an oligomerization reaction involving activated thioglycoside monomers, consisting of a 2-deoxy sugar unit. The oligomerization promoter plays an important role in the formation of either the cyclic- or the linear oligosaccharides. Encapsulation abilities of a 2-deoxy cyclic hexamer with p-nitrophenot, by a H-1 NMR method, showed complexation of the guest molecule with the host molecule. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2008.10.026