1,1'-[(ethane-1,2-diyldioxy)di-o-phenylene]bis(indoline-2,3-dione) | 1280740-24-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 1,1'-[(ethane-1,2-diyldioxy)di-o-phenylene]bis(indoline-2,3-dione)
• 英文别名: 1,1'-((Ethane-1,2-diyldioxy)di-o-phenylene)bis(indoline-2,3-dione)；1-[[2-[2-[2-[(2,3-dioxoindol-1-yl)methyl]phenoxy]ethoxy]phenyl]methyl]indole-2,3-dione
• CAS: 1280740-24-0
• 化学式: C₃₂H₂₄N₂O₆
• 分子量: 532.552
• InChiKey: XKZXJDDWVYOCHX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  40
• 可旋转键数：
  9
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  93.2
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  silver hexafluoroantimonate 、 1,1'-[(ethane-1,2-diyldioxy)di-o-phenylene]bis(indoline-2,3-dione) 以 二氯甲烷 、 苯 为溶剂， 以48%的产率得到bis(μ-1,1'-[(ethane-1,2-diyldioxy)di-o-phenylene]bis(indoline-2,3-dione))disilver(I) bis(hexafluoridoantimonate)
  参考文献：
  名称：

  1,1′-[(Ethane-1,2-diyldioxy)di-o-phenylene]bis(indoline-2,3-dione) (L) and a novel [Ag₂L₂]²⁺metallocycle based on coordination-driven Ag—O and Ag—π bonds

  摘要：

  1,1'-[(Ethane-1,2-diyldioxy)di-o-phenylene]bis(indoline-2,3-dione), C32H24N2O6, L or (I), adopts a trans conformation with the two terminal indoline-2,3-dione groups located on opposite sides of the central ether bridge, as required by a centre of inversion located at the mid-point of the ethane C-C bond. However, in the discrete binuclear AgI metallocycle complex salt bis{mu-1,1'-[(ethane-1,2-diyldioxy)di-o-phenylene]bis(indoline-2,3-dione)}disilver(I) bis(hexafluoridoantimonate), [Ag-2(C32H24N2O6)(2)][SbF6](2), (II), synthesized by combination of L with AgSbF6, L adopts a gauche conformation to bind AgI via the two indolinedione O atoms and two C atoms from the phenoxy ring. One dione O atom from the opposite side of the ether bridge completes the irregular coordination environment of each AgI atom. The complex is on a centre of inversion located between the AgI atoms. In the solid state, these binuclear [Ag-2 L (2)]2+ metallocycles stack together via intermolecular pi-pi interactions to generate a one-dimensional chain motif, with the [SbF6]- counter-ions, which are disordered, located between the chains.

  DOI：

  10.1107/s0108270110054697