7,14-bis(2-methoxyphenyl)-5,12-dimethyl-1,4,8,11-tetraazacyclotetradecane copper(II) perchlorate | 922172-60-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 7,14-bis(2-methoxyphenyl)-5,12-dimethyl-1,4,8,11-tetraazacyclotetradecane copper(II) perchlorate
• CAS: 922172-60-9
• 化学式: C₂₆H₄₀Cl₂CuN₄O₁₀
• 分子量: 703.076
• InChiKey: LZQNMEFVYRCWMV-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  copper(II) perchlorate hexahydrate 、 7,14-bis(2-methoxyphenyl)-5,12-dimethyl-1,4,8,11-tetraazacyclotetradecane 以 甲醇 为溶剂， 以93%的产率得到7,14-bis(2-methoxyphenyl)-5,12-dimethyl-1,4,8,11-tetraazacyclotetradecane copper(II) perchlorate
  参考文献：
  名称：

  Complexes of pendant-armed cyclam derivatives with copper(II) perchlorate: Synthesis and crystal structures

  摘要：

  A designed series of cyclam type macrocyclic ligands 1-3 that feature a different degree of saturation and number of functional appendages of the macroring, including preparation of the respective Cu(II) perchlorate complexes 1a-3a, was synthesized. Comparative discussion of the X-ray crystal structures of the free ligands and the corresponding complexes shows that dependent on the structure of the compound, transanular, pendant arm and anion involving conventional and weaker H bond contacts are operating. In the complexes, the coordination environment around the Cu(II) cation is distorted octahedral with the nitrogens of the macroring defining the equatorial sites and either two oxygens, each of a perchlorate anion, or the lateral pyridine nitrogens in apical positions. Thus, only the pyridine containing pendants in 3a proved effective in metal ion coordination while the anisyl groups are engaged in H bonding, respectively. The uncomplexed macrocycle 3 yielded an inclusion compound with chloroform, also indicating a special ability relating to this series of compounds. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.06.037