Y(hydrogen oxydiacetate)3 * oxydiacetic acid * H2O | 215531-49-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Y(hydrogen oxydiacetate)3 * oxydiacetic acid * H2O
• CAS: 215531-49-0
• 化学式: C₄H₆O₅*C₁₂H₁₅O₁₅Y*H₂O
• 分子量: 640.252
• InChiKey: ISVHULIXASWINL-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二甘醇酸 、 yttrium(III) oxide 以 水 为溶剂， 以70%的产率得到Y(hydrogen oxydiacetate)3 * oxydiacetic acid * H2O
  参考文献：
  名称：

  Synthesis and X-ray crystal determination of four novel lanthanide (III) oxydiacetate complexes

  摘要：

  Four new lanthanide oxydiacetates [{Y(Hoda)(3)}. H(2)odaH(2)O] (1), [{Y-2(oda)(3)(H2O)(4). 2H(2)O}(n)] (2), [{LaGd(oda)(3)(H2O)(3). 6H(2)O}(n)] (3) and [{LaY (oda)(3)(H2O)(3). 6H(2)O}(n)] (4) (oda = -O2CCH2OCH2CO2-) have been synthesized and their structures determined by single-crystal X-ray methods. Compound 1 is monometallic with distorted YO9 units formed via coordination of three tridentate Hoda ligands. Compound 2 consists of polymeric sheets of YO9 units formed via coordination of three tridentate oda ligands bridged through carboxylate groups to YO8 units. Compounds 3 and 4 are isomorphous heterobimetallic three-dimensional networks of LnO(9) units (Ln = Gd or Y) formed via coordination of three tridentate oda ligands bridged to the larger radius La(III) in LaO9 units through carboxylate groups. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00131-5