[acetylacetone thiobenzoylhydrazonato(2-)]-triphenylphosphane-nickel(II) | 210584-31-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: [acetylacetone thiobenzoylhydrazonato(2-)]-triphenylphosphane-nickel(II)
• CAS: 210584-31-9
• 化学式: C₃₀H₂₇N₂NiOPS
• 分子量: 553.287
• InChiKey: NGHVNDYSNBHIIQ-NKXRBYANSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(triphenylphosphine)nickel(II) chloride 、 acetylacetone thiobenzoylhydrazone 以 二氯甲烷 为溶剂， 以50%的产率得到[acetylacetone thiobenzoylhydrazonato(2-)]-triphenylphosphane-nickel(II)
  参考文献：
  名称：

  Ligand exchange reactions of ReCl4(PPh3)2, ReOCl3(PPh3)2 and NiCl2(PPh3)2 with acetylacetone thiobenzoylhydrazone. An unexpected template reaction at the ReO3+ core. Molecular structures of the resulting oxorhenium(V) and nickel complexes

  摘要：

  The ligand exchange reactions of ReCl4(PPh3)(2), ReOCl3(PPh3)(2) and NiCl2(PPh3)(2) with acetylacetone thiobenzoylhydrazone have been studied. An unexpected template reaction at the ReO3+ core forming the new tetradentate triacidic ligand triacetylmethane bis(thiobenzoylhydrazone) will be described and discussed. The final products were characterized by elemental analysis, mass spectroscopy, H-1 NMR, IR, W-VIS spectroscopy and X-ray structural analysis. [Acetylacetone thiobenzoylhydrazonato(2-)]chloro-oxorhenium(V) was isolated as an intermediate. The crystal structures have been determined cf [triacetylmethane bis( thiobenzoylhydrazonato) (3-)-S,S',N,N'] oxorhenium(V) C21H19N4O2S2Re, monoclinic P2(1)/m, a = 7.451 (1), b = 11.262(3), c = 12.639(4) Angstrom, beta = 90.66(2)degrees, Z = 2, R-1 = 0.0445, and [acetylacetone thiobenzoylhydrazonato(2-)]-triphenylphosphane-nickel (II) C30H27N2OSPNi, orthorhombic Pbca, a = 16.658(2), b = 14.725(2), c = 21.950(2) Angstrom, Z = 8, R-1 = 0.0283. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(97)06154-9