1-hydroxy-3-phenoxypropan-2-yl methacrylate | 88189-67-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-hydroxy-3-phenoxypropan-2-yl methacrylate
• 英文别名: 1-Hydroxy-3-phenoxypropan-2-yl 2-methylprop-2-enoate；(1-hydroxy-3-phenoxypropan-2-yl) 2-methylprop-2-enoate
• CAS: 88189-67-7
• 化学式: C₁₃H₁₆O₄
• 分子量: 236.268
• InChiKey: DMLSPVIUHNJSME-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  17
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  甲基丙烯酸 、 苯基缩水甘油醚 在 chromium(lll) acetate 作用下， 反应 80.0h， 生成 甲基丙烯酸-2-羟-3-苯氧基丙酯 、 1-hydroxy-3-phenoxypropan-2-yl methacrylate
  参考文献：
  名称：

  乙酸铬 (III) 存在下某些羧酸与某些环氧化物反应的反应性

  摘要：

  在乙酸铬 (III) 存在下，比较了乙酸、丙烯酸和甲基丙烯酸在与环氧氯丙烷、苯基缩水甘油醚、乙酸缩水甘油酯和甲基丙烯酸缩水甘油酯的反应中的反应性。相对于环氧乙烷系列，酸反应性变化不同。还观察到溶剂对酸与表氯醇反应的影响。

  DOI：

  10.1021/op010112q

文献信息

• AROMATIC GLYCOL ETHERS AS WRITING MONOMERS IN HOLOGRAPHIC PHOTOPOLYMER FORMULATIONS
  申请人：COVESTRO DEUTSCHLAND AG

  公开号：US20170045816A1

  公开（公告）日：2017-02-16

  The invention relates to a photopolymer formulation comprising specific aromatic glycol ethers as writing monomers, matrix polymers and a photoinitiator. The invention further provides an unexposed holographic medium obtainable using an inventive photopolymer formulation, and an exposed holographic medium obtainable by exposing a hologram into an inventive unexposed holographic medium. The invention likewise provides a visual display comprising an inventive exposed holographic medium, for the use of an inventive exposed holographic medium for production of chip cards, identification documents, 3D images, product protection labels, labels, banknotes or holographic optical elements, and specific aromatic glycol ethers.

  本发明涉及一种光聚合配方，包含特定的芳香族乙二醇醚作为写入单体、基质聚合物和光引发剂。本发明还提供了一种使用创新光聚合配方可获得的未曝光全息介质，以及通过将全息图曝光到创新的未曝光全息介质中获得的曝光全息介质。本发明同样提供了一种包含创新曝光全息介质的视觉显示，用于创新曝光全息介质在生产芯片卡、身份证件、三维图像、产品保护标签、标签、钞票或全息光学元件中的应用，以及特定的芳香族乙二醇醚。
• Hydrophobic intraocular lens
  申请人：Benz Research and Development Corp.

  公开号：US10196470B2

  公开（公告）日：2019-02-05

  A hydrophobic intraocular lens (IOL) with excellent non-glistening characteristics, high Abbe number, excellent mechanical properties comprising at least one copolymer comprising: (a) a first monomeric subunit comprising a polymerized (meth)acrylate group and at least one alkoxyalkoxyalkyl side group, (b) a second monomeric subunit different from the first monomeric subunit comprising a polymerized (meth)acrylate group, at least one side group comprising (i) an aryloxy moiety with at least one halogen, and (ii) an aliphatic carbon moiety linking the aryloxy moiety with the polymerized (meth)acrylate group, wherein the aliphatic carbon moiety comprises at least one hydroxyl substituent.

  一种疏水性眼内透镜（IOL），具有优异的不闪烁特性、高阿贝数和优异的机械性能，由至少一种共聚物组成，该共聚物包括(a) 由聚合的（甲基）丙烯酸酯基团和至少一个烷氧基烷氧基烷基侧基组成的第一单体亚基， (b) 与由聚合的（甲基）丙烯酸酯基团组成的第一单体亚基不同的第二单体亚基、至少一个侧基包括：(i) 带有至少一个卤素的芳氧基，和 (ii) 连接芳氧基和聚合的（甲基）丙烯酸酯基团的脂肪族碳基，其中脂肪族碳基包括至少一个羟基取代基。
• High refractive index hydrophilic materials
  申请人：Benz Research and Development Corp.

  公开号：US10894111B2

  公开（公告）日：2021-01-19

  A hydrophilic intraocular lens (IOL) with high refractive index comprising at least one copolymer comprising: ((a) a first monomeric subunit comprising (i) a polymerized (meth)acrylate group and an aliphatic carbon moiety comprising at least two hydroxyl substituents or (ii) a polymerized (meth)acrylamide group, (b) a second monomeric subunit different from the first monomeric subunit comprising a polymerized (meth)acrylate group, at least one side group comprising (i) an aryloxy moiety comprising at least one halogen, and (ii) an aliphatic carbon moiety linking the aryloxy moiety with the polymerized (meth)acrylate group, wherein the aliphatic carbon moiety comprises optionally at least one hydroxyl substituent, (c) a third monomeric subunit different from the first and second monomeric subunits comprising a polymerized (meth)acrylate group and at least one alkoxyalkoxyalkyl side group.

  一种具有高折射率的亲水性眼内透镜（IOL），由至少一种共聚物组成，共聚物包括(a) 第一单体亚基，包含(i)聚合的(甲基)丙烯酸酯基团和包含至少两个羟基取代基的脂肪族碳分子，或(ii)聚合的(甲基)丙烯酰胺基团；(b) 第二单体亚基，不同于包含聚合的(甲基)丙烯酸酯基团的第一单体亚基，至少一个侧基包含(i)包含至少一个卤素的芳氧基分子，和(ii)连接芳氧基分子的脂肪族碳分子、和(ii)连接芳氧基和聚合(甲基)丙烯酸酯基团的脂肪族碳基，其中脂肪族碳基任选包括至少一个羟基取代基， (c) 不同于第一和第二单体亚基的第三单体亚基，包括聚合(甲基)丙烯酸酯基团和至少一个烷氧基烷基侧基。
• Kinetic Study of Addition of Some Carboxylic Acids to 1,2-Epoxy-3-phenoxypropane
  作者：Agnieszka Bukowska、Wiktor Bukowski

  DOI：10.1021/op9900479

  日期：1999.11.1

  The kinetics of addition of acetic, acrylic, or methacrylic acids to 1,2-epoxy-3-phenoxypropane (glycidyl phenyl ether) carried out in the presence of chromium(III) ethanoate have been studied. A kinetic model of the reaction has been proposed. The rake constants as web as the activation parameters have been evaluated. The reactivity of the acids in reactions with GPE and 1-chloro-2,3-epoxypropane (epichlorohydrin) without any solvent are compared. The compositions of reaction mixtures have been carefully determined.
• HYDROPHOBIC INTRAOCULAR LENS
  申请人：Benz Research And Development Corporation

  公开号：EP3458118B1

  公开（公告）日：2021-10-27