| 166898-33-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 166898-33-5
• 化学式: C₆₃H₇₀NO₁₁Tb
• 分子量: 1176.17
• InChiKey: ZZRJEOCVWINMJT-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  terbium(III) chloride hexahydrate 、 <<15,35,55,75-tetra-tert-butyl-72-<<<(1-naphthalene)methyl>carbamoyl>methoxy>-1,3,5,7-tetrabenzocyclooctophane-12,32,52-triyl>trioxy>triacetic acid 在 三乙胺 作用下， 以 乙腈 为溶剂， 以100%的产率得到
  参考文献：
  名称：

  New Sensitizer-Modified Calix[4]arenes Enabling Near-UV Excitation of Complexed Luminescent Lanthanide Ions

  摘要：

  The synthesis is described of a series of calix[4]arenes with three different sensitizer chromophores (''antenna'') attached to the lower rim via a short spacer. In the Eu3+ and Tb3+ complexes of these calixarenes, photoexcitation of the antenna can induce lanthanide emission via intramolecular energy transfer. Although the higher energy of the Tb3+ luminescent state makes it more difficult to sensitize than in the case of Eu3+, especially a triphenylene antenna is found to have strong sensitizing ability toward not only Eu3+ but also Tb3+, allowing excitation of the lanthanide with wavelengths extending to 350 nm.

  DOI：

  10.1021/ja00142a004