genipocyanin G₁ | 104359-67-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: genipocyanin G₁
• 英文别名: Genipocyanin G1；2-[5-[(E)-[2-(carboxymethyl)-4-methoxycarbonyl-5-methylcyclopenta[c]pyridin-2-ium-7-ylidene]methyl]-4-methoxycarbonyl-7-methylcyclopenta[c]pyridin-2-yl]acetate
• CAS: 104359-67-3
• 化学式: C₂₇H₂₄N₂O₈
• 分子量: 504.496
• InChiKey: ZPRPDHOWGYISCZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  37
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  139
• 氢给体数：
  1
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  京尼平 、 聚甘氨酸 生成 genipocyanin G₁
  参考文献：
  名称：

  FUJIKAWA, SHIGEAKI;FUKUI, YUKO;KOGA, KUNIMASA;IWASHITA, TAKASHI;KOMURA, H+, TETRAHEDRON LETT., 28,(1987) N 40, 4699-4700

  摘要：

  DOI：

文献信息

• Structure of genipocyanin G1, a spontaneous reaction product between genipin and glycine
  作者：Shigeaki Fujikawa、Yuko Fukui、Kunimasa Koga、Takashi Iwashita、Hajime Komura、Kyosuke Nomoto

  DOI：10.1016/s0040-4039(00)96601-2

  日期：1987.1

  A spontaneous reaction of genipin and glycine gave a blue dimeric 1:1 adduct, whose structure was determined as 1 based on instrumental analyses, in particular, nOe experiments in 1H-NMR spectroscopy.

  genipin和甘氨酸的自发反应产生蓝色的二聚体1：1加合物，根据仪器分析，特别是1 H-NMR光谱中的nOe实验，其结构确定为1。
• Colorant Compounds Derived from Genipin or Genipin Containing Materials
  申请人：ECOFLORA S.A.S.

  公开号：US20180127587A1

  公开（公告）日：2018-05-10

  The present disclosure provides colorant compounds and methods of isolation of the colorant compounds derived from a reaction of genipin and an amine. The colorant compositions comprise purified compounds (e.g., a purified polymer or a purified dimer) obtained from multiple fractioning by chromatography of the reaction resulting material. The purified polymer or dimer can be used as a colorant by itself or in combination with another colorant for imparting color to a food, a drug, a cosmetic, a medical device, and textile products.
• US9890286B2
  申请人：——

  公开号：US9890286B2

  公开（公告）日：2018-02-13