1,8,15,22-tetranitrophthalocyanatocopper (II) | 121189-61-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: 1,8,15,22-tetranitrophthalocyanatocopper (II)
• 英文别名: copper tetranitrophthalocyanine；copper tetra-3-nitrophthalocyanine；Cu(II) 1,8,15,22-tetranitrophthalocyanine；copper(II) 3,3',3'',3'''-tetranitro phthalocyanine；[Cu(Pc(3-NO2)4)]；Copper(II) 1,8,15,22-tetra(nitro)phthalocyanine；copper;5,14,23,32-tetranitro-2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13(18),14,16,19(39),20,22(27),23,25,28,30(37),31(36),32,34-nonadecaene
• CAS: 121189-61-5
• 化学式: C₃₂H₁₂CuN₁₂O₈
• 分子量: 756.069
• InChiKey: NFKMKSVMZUESKI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.76
• 重原子数：
  53
• 可旋转键数：
  0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  259
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  1,8,15,22-tetranitrophthalocyanatocopper (II) 在 sodium sulfide nonahydrate 作用下， 以 水 为溶剂， 生成 1,8,15,22-tetraaminophthalocyanatocopper (II)
  参考文献：
  名称：

  Synthesis, structural investigations and biological studies on symmetrically substituted 3,3′,3",3"′-tetra-methoxyphenylimino phthalocyanine complexes

  摘要：

  The present paper describes the synthesis and characterization of novel metal (II) 3,3',3aEuro(3),3aEuro '-tetramethoxyphenylimino substituted phthalocyanines (M-MeOPhImPcs) of copper (II), cobalt (II), nickel (II) and zinc (II) by condensing the 3,3',3aEuro(3),3aEuro(3)aEuro(2)-tetra amino phthalocyanines with anisaldehyde. The dark bluish green colored tetraimino substituted phthalocyanine derivatives were characterized by various physico-chemical techniques like elemental analysis, magnetic susceptibility, electronic, IR, powder X-ray diffraction and thermo gravimetric analysis (TGA) to check the structural integrity and purity. The variations of magnetic moment as a function of field strength indicated the presence of inter molecular co-operative interactions. The complexes were also evaluated for their antifungal and antibacterial activities.

  DOI：

  10.1134/s0036023608010117
• 作为产物：
  描述：

  3-硝基邻苯二甲酸酐 、 copper(II) acetate monohydrate 在 ammonium molybdate 、 尿素 作用下， 以 硝基苯 为溶剂， 以49%的产率得到1,8,15,22-tetranitrophthalocyanatocopper (II)
  参考文献：
  名称：

  Negrimovskii, V. M.; Derkacheva, V. M.; Kaliya, O. L., Journal of general chemistry of the USSR, 1991, vol. 61, p. 419 - 428

  摘要：

  DOI：

文献信息

• Synthesis, Magnetic, Spectral and Therhal Studies on Iietal(II) 1,8,15,224 Tetrantrophthalocyanines
  作者：M. P. Somashekarappa、J. Keshavayya

  DOI：10.1080/00945719909349486

  日期：1999.5
• TURKER, LEMI;OKER, LEVENT, DYES AND PIGM., 13,(1990) N, C. 81-92
  作者：TURKER, LEMI、OKER, LEVENT

  DOI：——

  日期：——
• KATAI, SYUNDZI;FUKUMOTO, YUDZI
  作者：KATAI, SYUNDZI、FUKUMOTO, YUDZI

  DOI：——

  日期：——
• EHXASI, SIGEHYUKI;SAKAMOTO, KI;SUDA, YASUMASA
  作者：EHXASI, SIGEHYUKI、SAKAMOTO, KI、SUDA, YASUMASA

  DOI：——

  日期：——