cobalt tetra-4-acetylaminotetra-5-nitrophthalocyanine | 438491-91-9

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: cobalt tetra-4-acetylaminotetra-5-nitrophthalocyanine
• 英文别名: CoPc(4-NHC(O)CH3)4(5-NO2)4
• CAS: 438491-91-9
• 化学式: C₄₀H₂₄CoN₁₆O₁₂
• 分子量: 979.724
• InChiKey: HHHIOXDQJNOYDW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cobalt tetra-4-acetylaminotetra-5-nitrophthalocyanine 在 sodium hydroxide 作用下， 以 sodium hydroxide 为溶剂， 以72%的产率得到cobalt tetra-4-aminotetra-5-nitrophthalocyanine
  参考文献：
  名称：

  摘要：

  The reaction of 4-acylamino-5-nitrophthalocyanines with cobalt(II) chloride was used to prepare for the first time the corresponding cobalt phthalocyanines, Hydrolysis of cobalt(II) tetra-4-acetylamino-tetra5-nitrophthalocyanine gave cobalt(II) tetra-4-aminotetra-5-nitrophthalocyanine. The effect of amino(acylamino) and nitro groups on the properties of the metal complexes, particularly on their electronic absorption spectra, was demonstrated.

  DOI：

  10.1023/a:1015370001651
• 作为产物：
  描述：

  4-acetylamino-5-nitrophthalodinitrile 在 cobalt(II) chloride 作用下， 反应 1.0h， 以78%的产率得到cobalt tetra-4-acetylaminotetra-5-nitrophthalocyanine
  参考文献：
  名称：

  摘要：

  The reaction of 4-acylamino-5-nitrophthalocyanines with cobalt(II) chloride was used to prepare for the first time the corresponding cobalt phthalocyanines, Hydrolysis of cobalt(II) tetra-4-acetylamino-tetra5-nitrophthalocyanine gave cobalt(II) tetra-4-aminotetra-5-nitrophthalocyanine. The effect of amino(acylamino) and nitro groups on the properties of the metal complexes, particularly on their electronic absorption spectra, was demonstrated.

  DOI：

  10.1023/a:1015370001651

文献信息

• Bifunctional octasubstituted phthalocyanines. Synthesis and properties
  作者：G. P. Shaposhnikov、V. E. Maizlish、V. P. Kulinich

  DOI：10.1134/s1070363207010215

  日期：2007.1

  Data on the synthesis of bifunctional octasubstituted phthalocyanines are reported. Some specificities of their electronic absorption spectra, thermal stability, and other properties, depending on the substituent nature and central metal ion, are revealed.