3-羟基丙基己酸酯 | 6963-48-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 3-羟基丙基己酸酯
• 英文名称: 3-hydroxypropyl hexanoate
• 英文别名: hexanoic acid-(3-hydroxy-propyl ester)；Hexansaeure-(3-hydroxy-propylester)
• CAS: 6963-48-0
• 化学式: C₉H₁₈O₃
• 分子量: 174.24
• InChiKey: WABLATSSBBFMIL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  12
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

安全信息

• 海关编码：
  2915900090

反应信息

• 作为产物：
  描述：

  3H-呋喃并[3,4-d][1,3]苯并二氮卓-3-酮,1,4-二氢-5-甲基- 在 aluminum oxide 、 Oxone 、 水 作用下， 以 氯仿 为溶剂， 反应 10.0h， 以90%的产率得到3-羟基丙基己酸酯
  参考文献：
  名称：

  Oxone®: A Convenient Reagent for the Oxidation of Acetals

  摘要：

  对称的环状和非环状缩醛通过与Oxone®的氧化反应生成了相应的酯，产率良好。用相同试剂处理醇的四氢吡喃衍生物则导致醇的氧化再生。

  DOI：

  10.1055/s-1999-2703

文献信息

• Molecular Healing of Polymeric Materials, Coatings, Plastics, Elastomers, Composites, Laminates, Adhesives, and Sealants by Active Enzymes
  申请人：McDaniel C. Steven

  公开号：US20100210745A1

  公开（公告）日：2010-08-19

  Disclosed herein are polymeric materials such as a coating, a plastic, a laminate, a composite, an elastomer, an adhesive, or a sealant; a surface treatment such as a textile finish or a wax; a filler for such a polymeric material or a surface treatment that includes an enzyme such as an esterase (e.g., a lipolytic enzyme, a sulfuric ester hydrolase, an organophosphorus compound degradation enzyme), an enzyme (e.g., a lysozyme, a lytic transglycosylase) that degrades a cell wall and/or a cell membrane component, a biocidal or biostatic peotide, and/or a peptidase. Also disclosed herein are methods of altering a material's property such as service life, flexability, or rigidity, by incorporation of an enzyme into a material capable of being chemically crosslinked by the activity of a lipolytic enzyme, a hydrolase, and/or a urease.

  本文公开了一些聚合材料，如涂层、塑料、层压板、复合材料、弹性体、粘合剂或密封剂；一种表面处理，如纺织品涂层或蜡；一种填料，用于这样的聚合材料或表面处理，其中包括一种酶，如酯酶（例如，脂肪水解酶，硫酸酯水解酶，有机磷化合物降解酶），降解细胞壁和/或细胞膜成分的酶（例如，溶菌酶，裂解转糖基酶），生物杀菌或生物静态肽，以及/或肽酶。本文还公开了通过将酶纳入可通过脂肪水解酶、水解酶和/或脲酶的活性交联材料中来改变材料性能，如使用寿命、柔韧性或刚度的方法。
• Anti-fouling Paints and Coatings
  申请人：Reactive Surfaces LTD

  公开号：US20150191607A1

  公开（公告）日：2015-07-09

  Disclosed herein are polymeric materials such as a coating, a plastic, a laminate, a composite, an elastomer, an adhesive, or a sealant; a surface treatment such as a textile finish or a wax; a filler for such a polymeric material or a surface treatment that includes an enzyme such as an esterase (e.g., a lipolytic enzyme, a sulfuric ester hydrolase, an organophosphorus compound degradation enzyme), an enzyme (e.g., a lysozyme, a lytic transglycosylase) that degrades a cell wall and/or a cell membrane component, a biocidal or biostatic peptide, and/or a peptidase. Also disclosed herein are methods of altering a material's property such as service life, flexability, or rigidity, by incorporation of an enzyme into a material capable of being chemically crosslinked by the activity of a lipolytic enzyme, a hydrolase, and/or a urease.

  本文披露了聚合材料，例如涂层、塑料、层压材料、复合材料、弹性体、粘合剂或密封剂；表面处理，例如纺织品整理或蜡；填充剂，用于这种聚合材料或表面处理，包括酯酶（例如脂肪水解酶、硫酸酯水解酶、有机磷化合物降解酶）的酶，降解细胞壁和/或细胞膜成分的酶（例如溶菌酶、裂解转葡糖苷酶），生物杀菌或生物稳定肽，和/或肽酶。本文还披露了通过将酶并入能够通过脂肪水解酶、水解酶和/或脲酶的活性进行化学交联的材料中，改变材料性能（例如使用寿命、柔韧性或刚度）的方法。
• Facile oxidative hydrolysis of acetals to esters using hypervalent iodine(III)/LiBr combination in water
  作者：Waraporn Panchan、Supanimit Chiampanichayakul、Deanna L. Snyder、Siriporn Yodbuntung、Manat Pohmakotr、Vichai Reutrakul、Thaworn Jaipetch、Chutima Kuhakarn

  DOI：10.1016/j.tet.2010.01.098

  日期：2010.4

  The combination of (diacetoxy)iodobenzene (Phl(OAc)(2), DIB) and lithium bromide (LiBr) efficiently oxidized cyclic and acyclic acetals to the corresponding hydroxyalkyl carboxylic esters and simple esters in good to excellent yields The merits of this reaction are that it employs commercially available and non-explosive hypervalent iodine(III) reagent, water as the solvent, a short reaction tune, and mild reaction conditions (C) 2010 Elsevier Ltd All rights reserved
• Biphenyl derivative, nerve cell degeneration repairing or protecting agent and process for preparing a phenyl derivative contained in the agent
  申请人：OTSUKA PHARMACEUTICAL CO., LTD.

  公开号：EP0382213B1

  公开（公告）日：1995-05-10
• NOVEL COPOLYMER OF PHASE CHANGE MATERIAL FOR THERMAL MANAGEMENT OF PV MODULES
  申请人：Honeywell International Inc.

  公开号：US20140163176A1

  公开（公告）日：2014-06-12

  The present invention relates to phase change materials (PCMs) which may be used with photovoltaic (PV) modules. More specifically, solid/solid PCMs having a polyolefin backbone polymer and a crystallizable side chain are provided. Preferably, the solid/solid PCM has a copolymer backbone having a polyolefin repeating unit, and the crystallizable side chains are grafted onto the copolymer backbone. Most preferably, the copolymer is poly(ethylene-co-glycidyl methacrylate) (PE-co-GMA), and polyethylene glycol (PEG) is the crystallizable side chain. Photovoltaic modules and backsheets for photovoltaic modules having solid/solid PCMs are also provided.