zinc methyl 15¹-oxo-protopyropheophorbide-d | 1059195-65-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: zinc methyl 15¹-oxo-protopyropheophorbide-d
• CAS: 1059195-65-1
• 化学式: C₃₃H₂₈N₄O₅*Zn
• 分子量: 625.999
• InChiKey: UYLHZQLRCMCGBN-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  zinc methyl 15¹-oxo-protopyropheophorbide-d 在 吡啶 、 硼烷-叔丁基胺 作用下， 以 二氯甲烷 为溶剂， 生成 zinc methyl 13¹-deoxo-3-devinyl-13¹-hydroxy-3-hydroxymethyl-15¹-oxo-protopyropheophorbide-a
  参考文献：
  名称：

  Synthesis of Zinc 3-Hydroxymethyl-porphyrins Possessing Carbonyl Groups at the 13- and/or 15-Positions for Models of Self-Aggregative Chlorophylls in Green Photosynthetic Bacteria

  摘要：

  Zinc 3-hydroxymethyl-protopyropheophorbide-d derivatives 1, 2, and 3 possessing carbonyl group(s) at the 13/15-, 13-, and 15-positions, respectively, and 4 lacking the C=O group were prepared from naturally occurring chlorophyll-a. Zinc porphyrins 1 and 2 possessing the 13-C=O self-aggregated in an aqueous micellar solution, similarly to the self-aggregates of BChls-c/d/e in the main light-harvesting antenna systems of green photosynthetic bacteria, whereas 3 and 4 lacking the 13-C=O failed to make such well-ordered aggregates. These results indicated that both the presence of the C=O group and its situation at the 13-position were preferable for formation of the well-ordered J-aggregates.

  DOI：

  10.1021/jo8014402
• 作为产物：
  描述：

  zinc methyl 15¹-oxo-pyropheophorbide-d 在 吡啶 、 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 以 丙酮 为溶剂， 反应 0.17h， 以90%的产率得到zinc methyl 15¹-oxo-protopyropheophorbide-d
  参考文献：
  名称：

  Synthesis of Zinc 3-Hydroxymethyl-porphyrins Possessing Carbonyl Groups at the 13- and/or 15-Positions for Models of Self-Aggregative Chlorophylls in Green Photosynthetic Bacteria

  摘要：

  Zinc 3-hydroxymethyl-protopyropheophorbide-d derivatives 1, 2, and 3 possessing carbonyl group(s) at the 13/15-, 13-, and 15-positions, respectively, and 4 lacking the C=O group were prepared from naturally occurring chlorophyll-a. Zinc porphyrins 1 and 2 possessing the 13-C=O self-aggregated in an aqueous micellar solution, similarly to the self-aggregates of BChls-c/d/e in the main light-harvesting antenna systems of green photosynthetic bacteria, whereas 3 and 4 lacking the 13-C=O failed to make such well-ordered aggregates. These results indicated that both the presence of the C=O group and its situation at the 13-position were preferable for formation of the well-ordered J-aggregates.

  DOI：

  10.1021/jo8014402