phenyl-2 propen-1 yl amine | 77253-00-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: phenyl-2 propen-1 yl amine
• 英文别名: 2-Phenylprop-1-en-1-amine
• CAS: 77253-00-0
• 化学式: C₉H₁₁N
• mdl: MFCD19204731
• 分子量: 133.193
• InChiKey: JPLOYXGSMDQUFQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.111
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Tetramethylborazen 、 phenyl-2 propen-1 yl amine 以 苯 为溶剂， 以50%的产率得到1,1-dimethyl-N-(2-phenylprop-1-en-1-yl)boranamine
  参考文献：
  名称：

  Boron-Nitrogen Compounds. XV. Preparation of Vinylated Aminoboranes

  摘要：

  DOI：

  10.1021/ic50015a043
• 作为产物：
  描述：

  2-苯基丙醛 在 S,S-二苯基硫亚胺 作用下， 以 苯 为溶剂， 以40%的产率得到phenyl-2 propen-1 yl amine
  参考文献：
  名称：

  Reaction ofS,S-Diphenylsulfilimine with Aldehydes; A New Synthesis of Nitriles

  摘要：

  DOI：

  10.1055/s-1980-29299

文献信息

• [EN] ASYMMETRIC IMINE HYDROGENATION PROCESSES<br/>[FR] PROCEDES D'HYDROGENATION ASYMETRIQUE DES IMINES
  申请人：ABDUR-RASHID KAMALUDDIN

  公开号：WO2005056513A1

  公开（公告）日：2005-06-23

  A process for the catalytic hydrogenation or asymmetric hydrogenation of imines of Formula (I) to the corresponding amines of Formula (II) is provided in which R1 is aryl ; R2 is aryl, cyclic, alkyl, alkenyl or alkynyl; and R3 is alky l. The catalytic system includes a ruthenium complex containing (1) a diamine and (2) a diphosphine or two monodentate phosphines ligands. Such process also relates to the asymmetric hydrogenation of prochiral imines to the chiral amines using chiral ruthenium complexes bearing chiral diphosphines or chiral monodentate phosphines and chiral diamines.

  提供了一种用于催化氢化或不对称氢化Formula(I)的亚胺至对应的Formula(II)胺的过程，其中R1是芳基；R2是芳基、环状、烷基、烯基或炔基；R3是烷基。催化系统包括一个含有(1)二胺和(2)二膦或两个单齿膦配体的钌配合物。这种过程还涉及使用手性钌配合物进行的对映选择氢化的过程，该钌配合物带有手性二膦或手性单齿膦和手性二胺。
• Asymmetric Imine Hydrogenation Processes
  申请人：Abdur-Rashid Kamaluddin

  公开号：US20070293681A1

  公开（公告）日：2007-12-20

  A process for the catalytic hydrogenation or asymmetric hydrogenation of imines of Formula (I) to the corresponding amines of Formula (II) is provided in which R 1 is aryl; R 2 is aryl, cyclic, alkyl, alkenyl or alkynyl; and R 3 is alkyl. The catalytic system includes a ruthenium complex containing (1) a diamine and (2) a diphosphine or two monodentate phosphines ligands. Such process also relates to the asymmetric hydrogenation of prochiral imines to the chiral amines using chiral ruthenium complexes bearing chiral diphosphines or chiral monodentate phosphines and chiral diamines.

  提供了一种用于催化氢化或不对称氢化式(I)亚胺至相应氨基式(II)的过程，其中R1为芳基；R2为芳香基，环状，烷基，烯基或炔基；R3为烷基。催化系统包括一种含有(1)二胺和(2)二膦或两个单齿膦配体的钌配合物。这种过程还涉及使用手性二膦或手性单齿膦和手性二胺的手性钌配合物对非手性亚胺进行不对称氢化，制备手性氨基化合物。
• A dispersant/antioxidant viscosity index improving lubricant additive
  申请人：TEXACO DEVELOPMENT CORPORATION

  公开号：EP0435418A1

  公开（公告）日：1991-07-03

  Polymers having molecular weights of 20,000 to 2500,000 and exhibiting dispersant, antioxidant and viscosity index improving properties can be obtained by reacting aromatic nitroso compounds with base polymers derived from a first monomer which is an alkyl ester of acrylic acid or an alpha-alkyl substituted acrylic acid, and a second monomer which is polyunsaturated and has double bonds of different reactivity. Suitable second monomers are also esters, amides etc of acrylic or alpha alkyl substituted acrylic acid with unsaturated alcohols, amines, thiols or substituted phenols. Optionally a third monomer may be present, being preferably an aminoalkyl acrylamide or aminoalkyl alkyl acrylamide.

  将芳香族亚硝基化合物与基质聚合物反应，可得到分子量在 20,000 至 2500,000 之间并具有分散剂、抗氧化剂和粘度指数改善特性的聚合物，基质聚合物的第一单体是丙烯酸的烷基酯或α-烷基取代的丙烯酸，第二单体是多元不饱和且具有不同反应活性的双键。 第二种单体，它是多不饱和的，具有不同反应活性的双键。合适的第二单体也可以是丙烯酸或α-烷基取代丙烯酸与不饱和醇、胺、硫醇或取代酚的酯类、酰胺类等。第三种单体可以是氨基烷基丙烯酰胺或氨基烷基丙烯酰胺。
• PROCESS FOR PRODUCING OPTICALLY ACTIVE AMINES
  申请人：Mitsui Chemicals, Inc.

  公开号：EP0901996A1

  公开（公告）日：1999-03-17

  A novel process for producing an optically active amine is provided. The optically active amine is adapted for use as an intermediate in synthesizing physiologically active compounds such as pharmaceuticals and agricultural chemicals, as a functional material such as a liquid crystal, and as a starting material in synthesizing fine chemicals. The process comprises the step of reacting an imine with a hydride reagent in the presence of an optically active metal compound and an alcohol compound and/or carboxylic acid compound.

  提供了一种生产光学活性胺的新工艺。该光学活性胺可用作合成生理活性化合物（如药物和农药）的中间体、液晶等功能材料以及合成精细化学品的起始材料。该工艺包括以下步骤：在有光学活性金属化合物和醇类化合物和/或羧酸化合物存在的情况下，使亚胺与氢化物试剂发生反应。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.4, 4.9.2, page 166 - 181
  作者：

  DOI：——

  日期：——