[Cu(7,16-bis(5-chloro-2-hydroxybenzyl)-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane(-2H))] | 757238-04-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cu(7,16-bis(5-chloro-2-hydroxybenzyl)-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane(-2H))]
• CAS: 757238-04-3
• 化学式: C₂₆H₃₄Cl₂CuN₂O₆
• 分子量: 605.018
• InChiKey: YJTVLGJSJPKMEL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) nitrate trihydrate 、 7,16-bis(5-chloro-2-hydroxybenzyl)-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane 以 N,N-二甲基甲酰胺 为溶剂， 以80%的产率得到[Cu(7,16-bis(5-chloro-2-hydroxybenzyl)-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane(-2H))]
  参考文献：
  名称：

  Synthesis and crystal structure of copper complex of bis(p-chlorophenol)-containing diaza-18-crown-6 ligand

  摘要：

  A lariat crown ether ligand 7,16-bis (5-chloro-2-hydroxybenzyl)-1,4,10,13-tetraoxa-7,16-diazacyclo octadecane (H2L3) has been prepared via one-pot Mannich reaction. Reaction of H2L3 with Cu(NO3)(2) affords complex Cu-L-3. The complex was characterized by elemental analysis, IR and UV-visible spectroscopy. The crystal structure of the complex has been determined by X-ray diffraction study. The complexation results of Cu(NO3)(2) with diazacrown ethers containing different phenolic side arms are summarized and analyzed. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2004.05.016