8,9,19,20-TEtrakis[4-(1,1-dimethylethyl)phenoxy]bisbenzimidazo[2,1-a:1 inverted exclamation marka,2 inverted exclamation marka-b inverted exclamation marka]anthra[2,1,9-def:6,5,10-d'e'f inverted exclamation marka]diisoquinoline-6,11-dione | 185250-42-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 8,9,19,20-TEtrakis[4-(1,1-dimethylethyl)phenoxy]bisbenzimidazo[2,1-a:1 inverted exclamation marka,2 inverted exclamation marka-b inverted exclamation marka]anthra[2,1,9-def:6,5,10-d'e'f inverted exclamation marka]diisoquinoline-6,11-dione
• 英文别名: 18,21,36,40-tetrakis(4-tert-butylphenoxy)-7,14,25,32-tetrazaundecacyclo[21.13.2.22,5.03,19.04,16.06,14.08,13.020,37.025,33.026,31.034,38]tetraconta-1(36),2(40),3,5(39),6,8,10,12,16,18,20,22,26,28,30,32,34,37-octadecaene-15,24-dione
• CAS: 185250-42-4
• 化学式: C₇₆H₆₄N₄O₆
• 分子量: 1129.37
• InChiKey: VQBLRLXRTALYPR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  20.1
• 重原子数：
  86
• 可旋转键数：
  12
• 环数：
  15.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  107
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  邻苯二胺 、 1,6,7,12-四叔丁基苯氧基苝-3,4,9,10-四甲酸二酐 在 zinc(II) chloride 作用下， 以 喹啉 为溶剂， 生成 8,9,19,20-TEtrakis[4-(1,1-dimethylethyl)phenoxy]bisbenzimidazo[2,1-a:1 inverted exclamation marka,2 inverted exclamation marka-b inverted exclamation marka]anthra[2,1,9-def:6,5,10-d'e'f inverted exclamation marka]diisoquinoline-6,11-dione 、 7,8,18,19-TEtrakis[4-(1,1-dimethylethyl)phenoxy]bisbenzimidazo[2,1-a:2 inverted exclamation marka,1 inverted exclamation marka-a inverted exclamation marka]anthra[2,1,9-def:6,5,10-d'e'f inverted exclamation marka]diisoquinoline-10,21-dione
  参考文献：
  名称：

  新型苝-3,4:9,10-双(二甲酰亚胺)和苝-3,4:9,10-双(苯并咪唑)衍生物的合成、电化学和光吸收性能

  摘要：

  一系列在海湾被二或四取代的苝-3,4:9,10-双（二甲酰亚胺）（PBI）和苝-3,4:9,10-双（苯并咪唑）（PTCBI）衍生物通过给电子或吸电子基团的区域已被合成为可溶性 n 型半导体。光吸收光谱和电化学分析表明，湾区的取代性质在调节这些 PBI 和 PTCBI 衍生物的电子特性中起着至关重要的作用。根据理论研究确定的能级检查这些光学和电化学数据，可以建立结构和电子特性之间的关系。

  DOI：

  10.1002/ejoc.201100513

文献信息

• LUMINESCENT SOLAR COLLECTOR
  申请人：Bhaumik Kankan

  公开号：US20100043879A1

  公开（公告）日：2010-02-25

  Disclosed are fluorescent dye compounds of Formula (I) or (II): where R, R′, m and k are as described herein. The dye compounds are suitable for use in luminescent solar collectors. Methods of making the dye compounds and luminescent solar collectors comprising them are also described.
• SOLAR ENERGY FUNNELING USING THERMOPLASTICS FOR AGRICULTURAL APPLICATIONS
  申请人：Saudi Basic Industries Corporation

  公开号：US20140345195A1

  公开（公告）日：2014-11-27

  Disclosed is a wavelength-conversion material, and methods for its use, that includes an organic fluorescent dye and a polymeric matrix, wherein the organic fluorescent dye is solubilized in the polymeric matrix, and wherein the polymeric matrix is capable of absorbing light comprising a wavelength of 500 to 700 nm and emitting the absorbed light at a wavelength of greater than 550 to 800 nm.
• SOLAR ENERGY FUNNELING USING THERMOPLASTICS FOR ALGAE AND CYANOBACTERIA GROWTH
  申请人：SABIC GLOBAL TECHNOLOGIES B.V.

  公开号：US20160319231A1

  公开（公告）日：2016-11-03

  Disclosed is a wavelength conversion material for use in a photo-bioreactor for growing phototrophic organisms. The wavelength conversion material includes an organic fluorescent dye and a polymeric matrix, wherein the organic fluorescent dye is solubilized in the polymeric matrix. The wavelength-conversion material is capable of absorbing light comprising a wavelength of 280 to 650 nm and emitting the absorbed light at a wavelength of 400 to 800 nm.
• US8299354B2
  申请人：——

  公开号：US8299354B2

  公开（公告）日：2012-10-30
• US9204598B2
  申请人：——

  公开号：US9204598B2

  公开（公告）日：2015-12-08