| 200701-34-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• CAS: 200701-34-4
• 化学式: C₅₆H₆₀N₈Zn
• 分子量: 910.536
• InChiKey: RADCPGBCOMWFIK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  5,10,15,20-tetrakis(4-pyridyl)porphyrin zinc(II) 、 1-(n-butyl)-4,4'-bipyridinium 以 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  Preparation and characterization of water-soluble viologen-linked zinc porphyrin and bisviologen-linked zinc porphyrin

  摘要：

  Water-soluble viologen-linked zinc porphyrin (ZnP(C4VC4)(4)) and bisviologen-linked zinc porphyrin (ZnP(C4VAC4VB)(4)) were synthesized. In ZnP(C4VAC4VB)4(,) two viologens (butylviologen and 1-benzyl-1-butylvislogen) are connected with the tetrakis-(4-pyridyl)-zinc porphyrin via a methylene chain (-(CH2)(4-)), so as to produce a gradient of redox potential in the molecule. The photochemical and electrochemical properties of ZnP(C4VAC4VB), and ZnP(C4VC4)(4) were investigated by using the absorption spectra, the fluorescence spectra and the cyclic voltammetric measurement. The photoexcited triplet state of the porphyrin of ZnP(C4VAC4VB), and ZnP(C4VC4)(4) was studied by using a laser flash photolysis. In the case of ZnP(C4VAC4VB)(4), the photoexcited tripler state of the porphyrin was not quenched by the bonded viologen. On the other hand, for the ZnP(C4VC4)(4), the photoexcited triplet state of the porphyrin was quenched by the bonded viologen. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05623-5