[Ru(6,6'-dimethyl-2,2'-bipyridine)2(5,10-dihydro-2-(2-pyridyl)benzo[b]-1,5-naphthyridine)](2+) | 1201369-09-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯二氮卓类
• 英文名称: [Ru(6,6'-dimethyl-2,2'-bipyridine)2(5,10-dihydro-2-(2-pyridyl)benzo[b]-1,5-naphthyridine)](2+)
• 英文别名: [Ru(dmb)2(pbnHH)](2+)
• CAS: 1201369-09-6
• 化学式: C₄₁H₃₇N₇Ru
• 分子量: 728.862
• InChiKey: WAFICIBEMNXNSI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Ru(6,6'-dimethyl-2,2'-bipyridine)2(2-(2-pyridyl)benzo[b]-1,5-naphthyridine)](2+) 在 Na₂S₂O₄ 作用下， 以 not given 为溶剂， 生成 [Ru(6,6'-dimethyl-2,2'-bipyridine)2(5,10-dihydro-2-(2-pyridyl)benzo[b]-1,5-naphthyridine)](2+)
  参考文献：
  名称：

  Photochemical Stereospecific Hydrogenation of a Ru Complex with an NAD⁺/NADH-Type Ligand

  摘要：

  A polypyridylruthenium complex with an NAD(+)/NADH model ligand, [Ru(bpy)(2)(pbn)](2+) [bpy = 2,2'-bipyridine, pbn = 2-(2-pyridyl)benzo[b]-1,5-naphthyridine] in a D2O/CH3CN/triethylamine solution, undergoes stereospecific hydrogenation to give Delta-(S)- and Lambda-(R)- [Ru(bpy)(2)(pbnDD)](2+) [pbnDD = 5,10-dideutero-2-(2-pyridyl)benzo[b]-1,5-naphthyridine] upon visible-light irradiation. This result clearly indicates the pathway via the pi-stacked dimer of the deuterated one-electron-reduced species. The reduction of [Ru(bpy)(2)(pbn)](2+) with Na2S2O4 in D2O did not afford any stereospecific products. Furthermore, the more sterically crowded Ru complex, [Ru(dmb)(2)(pbn)](2+) (dmb = 6,6'-dimethyl-2,2'-bipyridine), did not produce the corresponding pbnDD species upon irradiation.

  DOI：

  10.1021/ic901935u