N-Trifluorvinyl-morpholin | 27096-49-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 恶嗪烷类
• 英文名称: N-Trifluorvinyl-morpholin
• 英文别名: 4-trifluorovinyl-morpholine；4-(1,2,2-Trifluoroethenyl)morpholine
• CAS: 27096-49-7
• 化学式: C₆H₈F₃NO
• 分子量: 167.131
• InChiKey: XBPQBVUYOKKMDK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  5

文献信息

• NITROGEN CONTAINING HYDROFLUOROETHERS AND METHODS OF USING SAME
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20170283365A1

  公开（公告）日：2017-10-05

  A hydrofluoroether compound is represented by the following general formula (1): wherein n is 1-2.

  氢氟醚化合物由以下一般式（1）表示：其中n为1-2。
• [EN] AMINE-CONTAINING CYCLIC HYDROFLUOROETHERS AND METHODS OF USING THE SAME<br/>[FR] HYDROFLUOROÉTHERS CYCLIQUES CONTENANT UNE AMINE ET LEURS PROCÉDÉS D'UTILISATION
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2017155735A1

  公开（公告）日：2017-09-14

  Described herein is a cyclic fluorinated compound of formula (I) where: L is O, CH2, or a covalent bond; X is selected from F or CF3, and Y is selected from H, F, or CF3, wherein when X is CF3 then Y is F and when Y is CF3 then X is F„ each Rf1 is independently selected from a linear or branched perfluorinated alkyl group comprising 1-8 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof; or the two Rf1 groups are bonded together to form a fluorinated ring structure comprising 4-8 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof; the -CFZ-CHAQ group is bonded to a ring carbon that is alpha to at least one O atom of the ring; A is selected from F, or CF3; Z is selected from H, F, or CF3; and Q is selected from (i) a F atom, (ii) a Cl atom, (iii) a linear, cyclic, or branched perfluorinated alkyl group comprising 1-8 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof, or (iv) a G(Rf2)e group, where G is an O atom or a N atom wherein: when Q is a Cl atom, then Z and A are F atoms; when G is O then e is 1, Z is H, F, or CF3; A is F; and Rf2 is a linear or branched perfluorinated alkyl group comprising 1-10 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof; when G is N then e is 2, and each Rf2 group is independently a linear or branched perfluorinated alkyl group comprising 1-8 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof or the two Rf2 groups are bonded together to form a fluorinated ring structure comprising 4-8 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof, with the proviso that when A is CF3 then Z is F, and when Z is CF3 then A is F.

  本文描述的是一个循环氟化合物，其化学式为(I)，其中：L为O、CH2或共价键；X从F或CF3中选择，Y从H、F或 中选择，当X为 时，Y为F，当Y为 时，X为F；每个Rf1独立地选择自由1-8个碳原子的线性或支链全氟烷基基团，并且可选地包含至少一个由O、N或其组合选择的连结原子；或两个Rf1基团结合在一起形成含有4-8个碳原子并且可选地包含至少一个由O、N或其组合选择的连结原子的氟化环结构；-CFZ-CHAQ基团与环的至少一个O原子的α位碳原子结合；A从F或 中选择；Z从H、F或 中选择；Q从(i)F原子、(ii)Cl原子、(iii)线性、环状或支链全氟烷基基团，包括1-8个碳原子，并且可选地包含至少一个由O、N或其组合选择的连结原子，或(iv)G(Rf2)e基团中选择，其中G为O原子或N原子，当Q为Cl原子时，Z和A为F原子；当G为O时，e为1，Z为H、F或 ，A为F，Rf2为包括1-10个碳原子的线性或支链全氟烷基基团，并且可选地包含至少一个由O、N或其组合选择的连结原子；当G为N时，e为2，每个Rf2基团独立地选择自由1-8个碳原子的线性或支链全氟烷基基团，并且可选地包含至少一个由O、N或其组合选择的连结原子，或两个Rf2基团结合在一起形成含有4-8个碳原子并且可选地包含至少一个由O、N或其组合选择的连结原子的氟化环结构，但A为 时，Z为F，Z为 时，A为F。
• [EN] ALLYLIC TERMINALLY UNSATURATED HYDROFLUOROAMINE AND ALLYLIC TERMINALLY UNSATURATED HYDROFLUOROETHER COMPOUNDS AND METHODS OF USING THE SAME<br/>[FR] HYDROFLUOROAMINE À INSATURATION TERMINALE ALLYLIQUE ET COMPOSÉS DE TYPE HYDROFLUOROÉTHER À INSATURATION TERMINALE ALLYLIQUE ET PROCÉDÉS POUR LEUR UTILISATION
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2017095732A1

  公开（公告）日：2017-06-08

  Described herein is an unsaturated fluorinated compound of formula (I) where X is O or N; Y is F or H; Z is F or CF3; and A is F or CF3 wherein when X is O, then n is 1, Y is H, Z is F, A is F, and Rf is a linear or branched perfluorinated alkyl group comprising 1 to 10 carbon atoms and optionally comprising at least one catenated O or N; and when X is N, then n is 2 and each Rf group are (i) independently selected from a linear or branched perfluorinated alkyl group comprising 1 to 8 carbon atoms and optionally comprising at least one catenated O or N; or (ii) bonded together to form a ring structure comprising 4 to 8 carbon atoms and optionally comprising at least one catenated O or N with the proviso that when Z is CF3 then A is F and when A is CF3 then Z is F and methods of making and using the same.

  本文描述了一种不饱和氟化合物，其化学式为（I），其中X为O或N；Y为F或H；Z为F或CF3；A为F或 ，其中当X为O时，n为1，Y为H，Z为F，A为F，Rf为包含1到10个碳原子的线性或支链全氟烷基基团，可选地包含至少一个连续的O或N；当X为N时，n为2，每个Rf基团（i）独立地选择自由包含1到8个碳原子的线性或支链全氟烷基基团，可选地包含至少一个连续的O或N；或（ii）结合在一起形成包含4到8个碳原子的环结构，可选地包含至少一个连续的O或N，但当Z为 时，A为F，当A为 时，Z为F，以及制备和使用这种化合物的方法。
• [EN] AMINE-CONTAINING ACYCLIC HYDROFLUOROETHERS AND METHODS OF USING THE SAME<br/>[FR] HYDROFLUOROÉTHERS ACYCLIQUES AMINÉS ET LEURS PROCÉDÉS D'UTILISATION
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2017155686A1

  公开（公告）日：2017-09-14

  An acyclic fluorinated compound of formula (I) is amine -containing acyclic hydrofluoroethers. The acyclic fluorinated compound is useful as heat transfer, solvent cleaning, fire extinguishing agents and electrolyte solvents and additives.

  一种无环氟化合物，化学式为(I)，是含胺的无环氢氟醚。该无环氟化合物可用作传热剂、溶剂清洗剂、灭火剂和电解质溶剂和添加剂。
• Amine-containing acyclic hydrofluoroethers and methods of using the same
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US10344006B2

  公开（公告）日：2019-07-09

  An acyclic fluorinated compound of formula (I) is amine-containing acyclic hydrofluoroethers. The acyclic fluorinated compound is useful as heat transfer, solvent cleaning, fire extinguishing agents and electrolyte solvents and additives.

  式（I）的无环含氟化合物是含胺的无环氢氟醚。无环含氟化合物可用作传热、溶剂清洗、灭火剂以及电解质溶剂和添加剂。