[Cu(triphenylphosphine)2(2,9-dimethyl-1,10-phenanthroline)](ClO4) | 161503-28-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [Cu(triphenylphosphine)2(2,9-dimethyl-1,10-phenanthroline)](ClO4)
• 英文别名: {Cu(2,9-dimethyl-1,10-phenanthroline)(PPh3)2}ClO4；[Cu(triphenylphosphine)₂(2,9-dimethyl-1,10-phenanthroline)](ClO₄)；[Cu(PPh₃)₂(dmp)](ClO₄)
• CAS: 161503-28-2
• 化学式: C₅₀H₄₂CuN₂P₂*ClO₄
• 分子量: 895.841
• InChiKey: XZISZAXSACLKSX-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cu(triphenylphosphine)2(2,9-dimethyl-1,10-phenanthroline)](ClO4) 在 methylviologen⁽²⁺⁾ 作用下， 以 乙醇 、 水 为溶剂， 生成 {Cu(2,9-dimethyl-1,10-phenanthroline)(PPh3)2}(2+)
  参考文献：
  名称：

  Sakaki; Koga; Hinokuma, Inorganic Chemistry, 1987, vol. 26, # 11, p. 1817 - 1819

  摘要：

  DOI：
• 作为产物：
  描述：

  tetrakis(acetonitrile)copper(I) perchlorate 、 三苯基膦 以 乙醇 为溶剂， 生成 [Cu(triphenylphosphine)2(2,9-dimethyl-1,10-phenanthroline)](ClO4)
  参考文献：
  名称：

  Photoinduced electron transfer between [Cu(dmphen)L₂]⁺[dmphen = 2,9-dimethyl-1,10-phenanthroline, L = PPh_n(C₆H₄OMe-p)_{3 –n}(n= 0–3)] and methyl viologen

  摘要：

  Photocatalytic reduction of methyl viologen (1,1'-dimethyl-4,4'-bipyridinium mv(2+)) was efficiently carried out with copper(I) complexes [Cu(dmphen)L(2)](+) [dmphen = 2,9-diinethyl-1,10-phenanthroline, L = PPh(n)(C(6)H(4)OMe-p)(3-n), n = 0-3] upon irradiation of the metal-o-ligand charge-transfer band at around 360 nm. The quantum yield for reduction, phi(mv(.+)), increases considerably in the order L = PPh(3) much less than PPh(2)(C(6)H(4)OMe-p) PPh(C(6)H(4)OMe-p)(2) < P(C(6)H(4)OMe-p), i.e. in increasing order of the phosphine donation ability. The best quantum yield (0.1) was recorded when [Cu(dmphen){P(C(6)H(4)OMe-p)(3)}(2)](+) was used. Kinetic analysis and measurement of the lifetime of the excited copper(I) complex revealed the reason why phi(mv(.+)) increases as the phosphine donation ability increases: first, the excited state becomes longer-lived and secondly, the charge-separation step becomes easier with increasing donation ability. The significant phosphine effects on the excited-state lifetime are discussed in terms of the solvent interaction with the copper(I) centre.

  DOI：

  10.1039/dt9960001909

文献信息

• Significant phosphine ligand effect on the photochemical reactivity of [Cu(N–N)L₂]⁺(N–N = 1,10-phenanthroline or 2,9-dimethyl-1,10-phenanthroline; L = tertiary phosphine)
  作者：Shigeyoshi Sakaki、Satoru Hashimoto、Genji Koga、Katsutoshi Ohkubo

  DOI：10.1039/dt9880001641

  日期：——