| 558452-39-4

• CAS: 558452-39-4
• 化学式: C₁₂H₁₀BF₄P
• 分子量: 271.99
• InChiKey: GXJFMVQBOBGFED-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 水 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  An arene–ruthenium(II) complex containing novel hybrid phosphinofluoro ligands

  摘要：

  In the title compound, (eta(6)-p-cymene)[(diphenylphosphinofluorido)trifluoroborato-kappa(2)P,F][(diphenylphosphinoylfluorido) trifluoroborato-kappaO]ruthenium(II), [Ru(C12H10BF4OP)(C12H10BF4P)(C10H14)], the hybrid Ph2PFBF3 ligand is bidentate (kappa(2)P,F) and thus forms a five-membered chelate ring. The Ph2PFBF3 ligand is unusually ligated to the metal through the P atom of the PPh2 moiety and through one of the F atoms of the BF4 moiety. The phosphine-oxidized Ph2P(O)FBF3 ligand is bonded to the Ru atom via the O atom. The Ru centre has a pseudo-octahedral coordination environment, in which the phenyl ring occupies three of the corners of the distorted octahedron. The Ru-O, Ru-F and Ru-P bond lengths are 2.107 (3), 2.135 (4) and 2.3145 (15) Angstrom, respectively.

  DOI：

  10.1107/s0108270103005808
• 作为产物：
  描述：

  二苯基氯化膦 、 silver tetrafluoroborate 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  An arene–ruthenium(II) complex containing novel hybrid phosphinofluoro ligands

  摘要：

  In the title compound, (eta(6)-p-cymene)[(diphenylphosphinofluorido)trifluoroborato-kappa(2)P,F][(diphenylphosphinoylfluorido) trifluoroborato-kappaO]ruthenium(II), [Ru(C12H10BF4OP)(C12H10BF4P)(C10H14)], the hybrid Ph2PFBF3 ligand is bidentate (kappa(2)P,F) and thus forms a five-membered chelate ring. The Ph2PFBF3 ligand is unusually ligated to the metal through the P atom of the PPh2 moiety and through one of the F atoms of the BF4 moiety. The phosphine-oxidized Ph2P(O)FBF3 ligand is bonded to the Ru atom via the O atom. The Ru centre has a pseudo-octahedral coordination environment, in which the phenyl ring occupies three of the corners of the distorted octahedron. The Ru-O, Ru-F and Ru-P bond lengths are 2.107 (3), 2.135 (4) and 2.3145 (15) Angstrom, respectively.

  DOI：

  10.1107/s0108270103005808