4,6-diphenyl-3-oxa-bicyclo[3.1.0]hexan-2-one | 6603-96-9

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 木脂素内酯
• 英文名称: 4,6-diphenyl-3-oxa-bicyclo[3.1.0]hexan-2-one
• 英文别名: 4,6-Diphenyl-3-oxa-bicyclo[3.1.0]hexan-2-on
• CAS: 6603-96-9
• 化学式: C₁₇H₁₄O₂
• 分子量: 250.297
• InChiKey: BUYASWTWIZDLMY-LSVZVQIISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.31
• 重原子数：
  19.0
• 可旋转键数：
  2.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  26.3
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  4,6-diphenyl-3-oxa-bicyclo[3.1.0]hexan-2-one 生成 1,4-二苯基-1,3丁二烯
  参考文献：
  名称：

  Stoermer; Schenck, Chemische Berichte, 1928, vol. 61, p. 2318

  摘要：

  DOI：
• 作为产物：
  描述：

  β-truxinamic acid 在 sodium hypochlorite 、 乙醚 、 氢溴酸 、 nitrosyl bromide 作用下， 生成 4,6-diphenyl-3-oxa-bicyclo[3.1.0]hexan-2-one
  参考文献：
  名称：

  Two possible hydrothermal vents in the northern Okinawa Trough

  摘要：

  As the Okinawa Trough is a back-are basin in early spreading, modern submarine hydrothermal activity and minerallization have many characteristics which have aroused wide attention. Up to now three well-known hydrothermal venting areas are all located in the middle part of the trough, During two cruise investigations to map and sample the seafloor numbers of Calyptogena sp, shells were dredged at two sites in the northern trough with comparatively thicker crust and numerous submarine volcanoes. Based on the fact that Calyptogena sp, is only observed around the hydrothermal vents and lives on hydrothermal activities, it is predicted that there is the possibility of modern hydrothermal activities in the northern part of the trough. In this note, the shell is carefully characterized and the sample locations with possible hydrothermal activity are given. it Is pointed out that the research of biogenic fossils to trace hydrothermal activity changes in venting time, strength fluctuations, evolution In chemical compositions and so on should be stressed in the future in addition to the study of the ecological characteristics of hydrothermal organisms.

  DOI：

  10.1007/bf02900472

文献信息

• Stoermer; Asbrand, Chemische Berichte, 1931, vol. 64, p. 2796,2798
  作者：Stoermer、Asbrand

  DOI：——

  日期：——