NiCl(2,6-bis(di-tert-butylphosphinito)pyridine)(CN) | 1350562-45-6

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: NiCl(2,6-bis(di-tert-butylphosphinito)pyridine)(CN)
• CAS: 1350562-45-6
• 化学式: C₂₂H₃₉N₂NiO₂P₂*Cl
• 分子量: 519.654
• InChiKey: YQKMICOKCXAHQG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  NiCl(2,6-bis(di-tert-butylphosphinito)pyridine)(CN) 、 四苯硼钠 、 苯 以 四氢呋喃 、 甲醇 为溶剂， 以84%的产率得到Ni(2,6-bis(di-tert-butylphosphinito)pyridine)(CN)(B(C6H5)4) benzene solvate
  参考文献：
  名称：

  Making M–CN bonds from M–Cl in (PONOP)M and (dippe)Ni systems (M=Ni, Pd, and Pt) using t-BuNC

  摘要：

  C-N bond activation of tert-butyl isocyanide in methanol using 2,6-bis(di-tert-butylphosphinito)pyridine (PONOP) metal (Ni, Pd, Pt) complexes and (dippe)NiCl2 are reported. t-BuOMe and t-BuCl were detected as organic products by GC-MS. Substitution of the metal-chloride by one molecule of tert-butyl isocyanide followed by carbonium ion loss/nucleophilic attack by chloride anion or methanol led to formation of a metal-cyanide bond. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.09.048
• 作为产物：
  描述：

  异氰酸叔丁酯 、 以 甲醇 为溶剂， 以26%的产率得到NiCl(2,6-bis(di-tert-butylphosphinito)pyridine)(CN)
  参考文献：
  名称：

  Making M–CN bonds from M–Cl in (PONOP)M and (dippe)Ni systems (M=Ni, Pd, and Pt) using t-BuNC

  摘要：

  C-N bond activation of tert-butyl isocyanide in methanol using 2,6-bis(di-tert-butylphosphinito)pyridine (PONOP) metal (Ni, Pd, Pt) complexes and (dippe)NiCl2 are reported. t-BuOMe and t-BuCl were detected as organic products by GC-MS. Substitution of the metal-chloride by one molecule of tert-butyl isocyanide followed by carbonium ion loss/nucleophilic attack by chloride anion or methanol led to formation of a metal-cyanide bond. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.09.048