| 928704-57-8

• CAS: 928704-57-8
• 化学式: C₄₂H₃₆CoPSi
• 分子量: 658.8
• InChiKey: MJPJEAAVKIXHBP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 三苯基膦 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of 4:5-Benzo-1-cobalta-2-silacyclopentenes and their Reactions with Alkynes and Alkenes:  An Expedient Route to Silicon-Containing Polycyclic Frameworks

  摘要：

  A convenient route to polycyclic compounds incorporating a silicon atom at a ring junction has been developed. Benzosilacyclobutenes tethered to alkynes or alkenes undergo intramolecular cycloadditions in the presence of CpCo(CO)(2). The incorporation of the CpCo(CO) moiety into the benzosilacyclobutene framework occurs regioselectively at the Ar-Si bond of the silacycle to give 1-cobalta-2-silacyclopentenes. On the basis of DFT/B3LYP calculations, a nonadiabatic mechanism involving changes in the spin state is proposed.

  DOI：

  10.1021/om0607245