A catalyst composition for improving the reaction-cure rate of polyurethane compositions derived from poly aliphatic isocyanate compounds and poly-hydroxyl bearing compounds is disclosed. The catalyst composition consists essentially of
(a) from about 25 to about 75 parts by weight of lead naphthenate; and
(b) from about 75 to about 25 parts by weight of at least one dialkyltin dicarboxylate compound of the formula:
wherein R is selected from C, to C. alkyl und R' is selected from C, to C,8 alkyl, based upon 100 parts by weight of said catalyst composition.
The catalyst compositions promote sufficiently rapid cure rates such that injection moldable poly aliphatic-isocyanate-based polyurethane compositions may be provided. In a preferred embodiment, new and improved integral skin foam polyurethane compositions are disclosed which may be reaction injection molded to form integral skin foam shaped articles exhibiting ultraviolet light resistance and improved colorability.
本发明公开了一种催化剂组合物,用于提高由多脂肪族
异氰酸酯化合物和多羟基化合物衍生的聚
氨酯组合物的反应固化速率。该催化剂组合物主要包括
(a) 约 25 至约 75 重量份的
环烷酸铅;和
(b) 至少一种式中的二烷基
锡二
羧酸化合物,按重量计,从约 75 至约 25 份:
其中 R 选自 C,至 C.烷基,R'选自 C,至 C,8烷基,以所述催化剂组合物 100 重量份计。
催化剂组合物能促进足够快的固化速率,从而提供可注射成型的聚脂族-
异氰酸酯基聚
氨酯组合物。在一个优选的实施方案中,公开了新的和改进的自结皮泡沫聚
氨酯组合物,该组合物可通过反应注塑形成自结皮泡沫状制品,具有抗紫外线和更好的着色性。