4,4'-(3-甲基-2,2-丁二基)二苯酚 | 3555-19-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4,4'-(3-甲基-2,2-丁二基)二苯酚
• 英文名称: dimethyl butylidene diphenol
• 英文别名: 2-Methyl-3,3-bis-<4-hydroxy-phenyl>-butan；2,2-bis-(4-hydroxy-phenyl)-3-methyl-butane；2,2-Bis-(4-hydroxy-phenyl)-3-methyl-butan；4,4'-(3-Methylbutane-2,2-diyl)diphenol；4-[2-(4-hydroxyphenyl)-3-methylbutan-2-yl]phenol
• CAS: 3555-19-9
• 化学式: C₁₇H₂₀O₂
• 分子量: 256.345
• InChiKey: KANXFMWQMYCHHH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-甲氧基苯基溴化镁 在 palladium on activated charcoal 、 氯化亚砜 、 乙醚 、 乙醇 、 氢溴酸 、 溶剂黄146 、 甲苯 作用下， 生成 4,4'-(3-甲基-2,2-丁二基)二苯酚
  参考文献：
  名称：

  The Structure and Toxicity of DDT Insecticides

  摘要：

  DOI：

  10.1021/ja01108a060

文献信息

• METHOD FOR PRODUCING CYANOGEN-HALIDE, CYANATE ESTER COMPOUND AND METHOD FOR PRODUCING THE SAME, AND RESIN COMPOSITION
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20150299110A1

  公开（公告）日：2015-10-22

  A method for efficiently producing a cyanogen halide with suppressed side effects, and a method for producing a high-purity cyanate ester compound at a high yield includes contacting a halogen molecule with an aqueous solution containing hydrogen cyanide and/or a metal cyanide, so that the hydrogen cyanide and/or the metal cyanide is allowed to react with the halogen molecule in the reaction solution to obtain the cyanogen halide, wherein more than 1 mole of the hydrogen cyanide or the metal cyanide is used based on 1 mole of the halogen molecule, and when an amount of substance of an unreacted hydrogen cyanide or an unreacted metal cyanide is defined as mole (A) and an amount of substance of the generated cyanogen halide is defined as mole (B), the reaction is terminated in a state in which (A):(A)+(B) is between 0.00009:1 and 0.2:1.

  一种用于高效生产抑制副作用的氰卤化物，以及以高收率生产高纯度氰酸酯化合物的方法包括将卤素分子与含有氢氰酸和/或金属氰化物的水溶液接触，使得氢氰酸和/或金属氰化物与卤素分子在反应溶液中发生反应以获得氰卤化物，其中基于1摩尔卤素分子使用超过1摩尔的氢氰酸或金属氰化物，当未反应的氢氰酸或未反应的金属氰化物的物质量定义为摩尔(A)，生成的氰卤化物的物质量定义为摩尔(B)，反应在(A)：(A)+(B)介于0.00009:1和0.2:1之间的状态中终止。
• BIS(AMINOPHENOL) DERIVATIVE, PROCESS FOR PRODUCING SAME, POLYAMIDE RESIN, POSITIVE PHOTOSENSITIVE RESIN COMPOSITION, PROTECTIVE FILM, INTERLAYER DIELECTRIC FILM, SEMICONDUCTOR DEVICE, AND DISPLAY ELEMENT
  申请人：Terakawa Koji

  公开号：US20100044888A1

  公开（公告）日：2010-02-25

  A bis(aminophenol) derivative having substituents at positions adjacent to two amino groups is provided. The bis(aminophenol) derivative is used as a raw material of a polyamide resin for a positive-tone photosensitive resin composition. A polyamide resin comprising bis(aminophenol) and a structure derived from a carboxylic acid is also provided, the bis(aminophenol) having substituents at positions adjacent to the two amino groups. A positive-tone photosensitive resin composition comprising a polybenzooxazole precursor resin, exhibiting high sensitivity and a high cyclization rate even when cured at a low temperature is provided. Also provided is a positive-tone photosensitive resin composition comprising a polyamide resin having an imide structure, an imide precursor structure, or an amide acid ester structure. The composition exhibits high sensitivity and produces a cured product having low water absorption even when cured at a low temperature.

  本发明提供了一种在两个氨基团相邻位置上具有取代基的双(氨基酚)衍生物。该双(氨基酚)衍生物用作聚酰胺树脂的原材料，用于制备正向感光树脂组合物。还提供了一种聚酰胺树脂，包括双(氨基酚)和由羧酸衍生的结构，其中双(氨基酚)在两个氨基团相邻位置上具有取代基。提供了一种正向感光树脂组合物，包括聚苯并噁唑前体树脂，即使在低温下固化，也表现出高灵敏度和高环化速率。还提供了一种正向感光树脂组合物，包括具有酰亚胺结构、酰亚胺前体结构或酰胺酸酯结构的聚酰胺树脂。该组合物表现出高灵敏度，即使在低温下固化，也能产生低吸水性的固化产物。
• Antistatic agents for resins, antistatic resin compositions, and molding of antistatic resins
  申请人：Kawakabe Hiroshi

  公开号：US20060100326A1

  公开（公告）日：2006-05-11

  The antistatic agent for resins of the present invention contains phosphonium salts represented by the general formula (1) below: (wherein R 1 , R 2 , and R 3 are each a straight-chain or branched alkyl group having 3 to 8 carbon atoms, and R 4 is a straight-chain or branched alkyl group having 10 to 22 carbon atoms; each alkyl group may have substituted hydroxy group or alkoxy group; R 1 , R 2 , and R 3 may be the same or different from each another; and X − is a tetrafluoroborate ion or a hexafluorophosphate ion).

  本发明的树脂抗静电剂包含以下通式（1）所表示的磷酰铵盐：（其中，R1、R2和R3分别为具有3至8个碳原子的直链或支链烷基，R4为具有10至22个碳原子的直链或支链烷基；每个烷基可能具有取代的羟基或烷氧基；R1、R2和R3可以相同也可以不同；X-为四氟硼酸盐离子或六氟磷酸盐离子）。
• Optical parts and sulfur-containing poly (thio)ester (co)polymer
  申请人：——

  公开号：US20030204030A1

  公开（公告）日：2003-10-30

  A poly(thio)ester (co)polymer which comprises a repeating structural unit represented by the formula (1-A) as an essential structural unit: 1 [wherein R 11 is a divalent aliphatic hydrocarbon group which may contain at least one sulfur atom in a sulfide group; R 12 is a mono- or poly-cyclic aliphatic or aromatic dicarboxylic acid residue; and X 11 and X 12 are each independently an oxygen atom or sulfur atom, and when X 11 and X 12 are the oxygen atoms, R 11 is a divalent aliphatic hydrocarbon group containing at least one sulfur atom in the sulfide group]; and an optical component obtainable by molding the poly(thio)ester (co)polymer. The poly(thio)ester (co)polymer is excellent in transparency and optical characteristics (e.g., a higher refractive index, higher Abbe number, and lower birefringence), and has also good mechanical characteristics and thermal characteristics, and further is excellent in melt fluidity and injection moldability.

  一种聚（硫）酯（共）聚合物，其包括由公式（1-A）表示的重复结构单元作为必要的结构单元：1 [其中，R11是一个双价的脂肪族碳氢基团，可以在硫化物基团中含有至少一个硫原子；R12是一个单环或多环的脂肪族或芳香族二羧酸残基；X11和X12分别是氧原子或硫原子，当X11和X12是氧原子时，R11是一个含有至少一个硫原子的双价脂肪族碳氢基团]；以及通过模塑聚（硫）酯（共）聚合物获得的光学组件。该聚（硫）酯（共）聚合物在透明度和光学特性（例如更高的折射率、更高的阿贝数和更低的双折射率）方面表现出色，同时具有良好的机械特性和热特性，并且在熔融流动性和注塑性方面表现出色。
• Thermoplastic resin composition with improved properties
  申请人：Kang Gon Tae

  公开号：US20070072995A1

  公开（公告）日：2007-03-29

  A thermoplastic composition and its use as a molded article and as housing or a part of electronic device are disclosed. The thermoplastic composition includes one or more of a polycarbonate resin, an ethylene-alkyl (meth)acrylate copolymer resin, a rubber modified vinyl graft copolymer resin, and a vinyl copolymer. The thermoplastic compositions described herein have one or more of improved impact strength, flowability, and thermal stability.

  本文揭示了一种热塑性组合物及其用途，可作为成型品和电子设备的外壳或零件。该热塑性组合物包括聚碳酸酯树脂、乙烯-烷基（甲）基丙烯酸酯共聚物树脂、橡胶改性乙烯基嵌段共聚物树脂和乙烯共聚物中的一种或多种。本文所描述的热塑性组合物具有改善的冲击强度、流动性和热稳定性中的一种或多种。