[[acetyloxy(trimethyl)-λ5-stibanyl]oxy-trimethyl-λ5-stibanyl] acetate | 85362-38-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: [[acetyloxy(trimethyl)-λ5-stibanyl]oxy-trimethyl-λ5-stibanyl] acetate
• CAS: 85362-38-5
• 化学式: C₁₀H₂₄O₅Sb₂
• 分子量: 467.798
• InChiKey: UPGCSEXZWIOSBR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  17.0
• 可旋转键数：
  4.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  61.83
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为产物：
  描述：

  silver(I) acetate 、 µ-oxybis[triphenylantimony(V)] chloride 以 二氯甲烷 为溶剂， 以81%的产率得到[[acetyloxy(trimethyl)-λ5-stibanyl]oxy-trimethyl-λ5-stibanyl] acetate
  参考文献：
  名称：

  Reactions of [SbR3X2]2O with carboxylates and the crystal structures of [SbPh3(O2CCF3)2]2O and [SbMe3(O2CCH3)2]2O

  摘要：

  Reactions of [SbPh3Br](2)O and [SbMe3Cl](2)O with a number of carboxylates lead to halogen substitution and formation of either [SbR3(O2CR')](2)O or SbR3(O2CR')(2). X-ray structures for two of the products, [SbPh3(O2CCF3)](2)O and [SbMe3(O2CCH3)](2)O, show that the carboxylates are unidentate. From NMR spectroscopy, the oxygen bridged compounds are hydrolysed by adventitious water giving SbR3(O2CR')OH in solution but when R = phenyl the original compounds can be recovered on crystallisation. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(97)00759-6