ZnI2(2-amino pyrimidine)2 | 142541-16-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: ZnI2(2-amino pyrimidine)2
• CAS: 142541-16-0
• 化学式: C₈H₁₀I₂N₆Zn
• 分子量: 509.407
• InChiKey: IYBHRRQHRLSPCA-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  1,3,5-三嗪-2,4,6-三胺,N,N'''-1,2-乙二基二[N-[3-[[4,6-二[丁基(2,2,6,6-四甲基-4-哌啶基)氨基]-1,3,5-三嗪-2-基]氨基]丙基]-N,N''-二丁基-N,N''-二(2,2,6,6-四甲基-4-哌啶基)- 、 zinc(II) iodide 以 丙酮 为溶剂， 生成 ZnI2(2-amino pyrimidine)2
  参考文献：
  名称：

  The IR and Raman spectra of 2-amino pyrimidine complexes of some Zn(II), Cd(II) and Hg(II) halides

  摘要：

  A series of complexes of the type HgX2(2-AMP) and MX2(2-AMP)2 where M = Zn(II) or Cd(II), X = Cl, Br or I and 2-AMP = 2 amino pyrimidine have been prepared, characterized and their IR and Raman spectra recorded. The IR spectra show that the ligand coordinates through the amino group, and that the heterocyclic nitrogens do not play an important role in coordination. The above conclusion is also supported by the H-1 and 19C NMR spectra. The far-IR and Raman spectra show that the HGX2(2-AMP) species possess a trans halogen-bridged structure of C2h symmetry, whereas the ZnI2(2-AMP)2 and CdI2(2-AMP)2 complexes are pseudotetrahedral of C2-upsilon symmetry.

  DOI：

  10.1016/0584-8539(92)80043-v

文献信息

• The preparation and thermal analysis studies on some first row transition metal complexes of 2-aminopyrimidine
  作者：J. R. Allan、G. M. Baillie、N. S. Middlemist、M. J. Pendlowski

  DOI：10.1007/bf01915689

  日期：1981.10