[nickel(II)bis(N-dodecylsalicylideneiminate)] | 35594-80-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: [nickel(II)bis(N-dodecylsalicylideneiminate)]
• CAS: 35594-80-0
• 化学式: C₃₈H₆₀N₂NiO₂
• 分子量: 635.597
• InChiKey: XKHMKOCJYRONCO-VLSRTVODSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  苯酚,2-[(十二基亚氨基)甲基]- 、 镍 以 甲醇 为溶剂， 生成 [nickel(II)bis(N-dodecylsalicylideneiminate)]
  参考文献：
  名称：

  Tribochemically active chelate complexes of salicylideneimines

  摘要：

  N-Alkylsalicylideneimines and their complexes with 3d metals were obtained by chemical (from metal salts) and electrochemical methods (from metals in the zero oxidation state). The compounds obtained were characterized by IR and H-1 NMR spectroscopy and X-ray diffraction analysis. According to crystallographic data, nickel bis(chelate) exists in the trans-planar configuration. A friction test revealed that the tribotechnical characteristics of lubricating formulations are substantially enhanced in the presence of N-alkylsalicylideneiminates.

  DOI：

  10.1134/s1070328409020067

文献信息

• Helicity Control of Supramolecular Gel Fibers Consisting of an Achiral Ni^IIComplex in a Chiral Nematic Solvent
  作者：Takatoshi Maeda、Yuuki Kuwajima、Takuya Akita、Yosuke Iwai、Naruyoshi Komiya、Yoshiaki Uchida、Takeshi Naota

  DOI：10.1002/chem.201801992

  日期：2018.8.27

  supramolecular chirality of aggregates consisting of achiral trans‐bis(salicylaldiminato)NiII complex 1 bearing long alkyl chains can be generated and controlled precisely in a chiral nematic liquid‐crystalline (LC) solvent, whereas the complex naturally forms achiral gel fibers in achiral nematic LC solvents and crystals in nonmesogenic solvents. The direction and intensity of the helicity of the gel fibers

  可以在手性向列液晶（LC）溶剂中精确生成并控制由带有长烷基链的非手性反式-双-（salicylaldiminato）Ni II复合物1形成的聚集体的超分子手性，而该复合物在非手性中自然形成非手性凝胶纤维向列型LC溶剂和非介晶溶剂中的晶体。凝胶纤维的螺旋度的方向和强度为1可以通过螺旋扭曲的性质和手性掺杂剂的浓度来调节处于LC凝胶状态的C -1。在LC凝胶的圆二色性（CD）光谱中以及通过直接SEM观察干燥的凝胶纤维，可以精确检测出螺旋度控制。XRD分析表明，该复合物基于人字形的层状排列的灵活性是凝胶纤维的LC特异性凝胶化和螺旋度控制的关键。