4,4'-亚丁基二(6-叔丁基-3-甲基苯基双十三烷基亚磷酸酯) | 13003-12-8

• 物质功能分类: 化学试剂 - 有机试剂 - 膦酸酯/膦酸盐
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4,4'-亚丁基二(6-叔丁基-3-甲基苯基双十三烷基亚磷酸酯)
• 中文别名: 4,4'-亚丁基双-(3-甲基-6-叔丁苯基)-四(十三烷基)二亚磷酸酯
• 英文名称: butylidenebis[2-tert-butyl-5-methyl-p-phenylene]-P,P,P',P'-tetratridecylbis(phosphine)
• 英文别名: [2-Tert-butyl-4-[1-[5-tert-butyl-4-di(tridecoxy)phosphanyloxy-2-methylphenyl]butyl]-5-methylphenyl] ditridecyl phosphite
• CAS: 13003-12-8
• 化学式: C₇₈H₁₄₄O₆P₂
• 分子量: 1239.95
• InChiKey: BWCBWCHWFIPXMJ-UHFFFAOYSA-N

物化性质

• 沸点：
  973.4±65.0 °C(Predicted)
• 物理描述：
  Liquid

计算性质

• 辛醇/水分配系数(LogP)：
  33.8
• 重原子数：
  86
• 可旋转键数：
  62
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  55.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  十三烷醇 、 4,4'-亚丁基双(6-叔丁基-3-甲基苯酚) 在 亚磷酸三苯酯 、 potassium hydroxide 作用下， 以61.8 g的产率得到4,4'-亚丁基二(6-叔丁基-3-甲基苯基双十三烷基亚磷酸酯)
  参考文献：
  名称：

  CN115304638

  摘要：

  公开号：

文献信息

• [EN] PHENOLIC METAL SALTS AND THEIR PHENOLIC ACIDS AS POLYMER STABILIZERS<br/>[FR] SELS MÉTALLIQUES PHÉNOLIQUES ET LEURS ACIDES PHÉNOLIQUES UTILISÉS COMME STABILISANTS DE POLYMÈRES
  申请人：BASF SE

  公开号：WO2019008002A1

  公开（公告）日：2019-01-10

  The invention relates to a composition comprising a) a polymer and b) (i) a phenolic metal salt of formula (I) Mn+ (L-)n wherein n is 1, 2 or 3, Mn+ is a metal ion and L- is an anion of formula (II) wherein A1 and A2 are both -CH2-CH2-, -CH=CH- or -CH2- or A1 is -CH=CH- and A2 is -CH2- or A1 is -CH2-CH2- and A2 is -CH2-, R1, R2, R4 and R5 are independently from each other C1-C4 alkyl, R3 is H or C1-C4 alkyl, or (ii) a bisphenolic compound of formula (III) wherein A1, A2, and R1 to R5 are as mentioned above, wherein the amount of component b) is from 0.0005 to 0.9 % by weight based on the weight of component a). The phenolic metal salt of formula (I) or the bisphenolic compound of formula (III) stabilizes the polymer against oxidative, thermal or light-induced degradation. Further embodiments are also an additive mixture comprising the phenolic metal salt of formula (I) or the bisphenolic compound of formula (III) and a further additive or a process for adding the component b) to the polymer, for example in an extruder.

  本发明涉及一种组合物，包括a）聚合物和b）（i）式（I）的酚类金属盐Mn+（L）n，其中n为1、2或3，Mn+为金属离子，L-为式（II）的阴离子，其中A1和A2均为-CH2- -，-CH=CH-或- -，或者A1为-CH=CH-，A2为- -或A1为- - -，A2为- -，R1、R2、R4和R5各自独立地为C1-C4烷基，R3为H或C1-C4烷基；或（ii）式（III）的双酚类化合物，其中A1、A2和R1至R5如上所述，其中组分b）的量为组分a）的重量的0.0005至0.9％。式（I）的酚类金属盐或式（III）的双酚类化合物可以使聚合物对氧化、热或光诱导降解具有稳定作用。进一步的实施方式还包括包括式（I）的酚类金属盐或式（III）的双酚类化合物和其他添加剂的混合物，或将组分b）添加到聚合物中的方法，例如在挤出机中。
• [EN] 3-PHENYL-BENZOFURAN-2-ONE DIPHOSPHATE DERIVATIVES AS STABILIZERS<br/>[FR] DÉRIVÉS DE 3-PHÉNYL-BENZOFURAN-2-ONE DIPHOSPHATE UTILISÉS COMME STABILISANTS
  申请人：BASF SE

  公开号：WO2019243267A1

  公开（公告）日：2019-12-26

  The invention relates to a composition comprising an organic material susceptible to oxidative, thermal or light-induced degradation and a compound of formula I-P, I-O or I-M. Further embodiments are a compound of formula I-P, I-O or I-M, a process for protection of the organic material by the compound, the use of the compound against degradation of the organic material, an additive composition comprising the compound, processes for manufacturing the compound and an intermediate involved therein.

  本发明涉及一种组合物，包括易于氧化、热降解或光降解的有机材料和公式I-P、I-O或I-M的化合物。进一步的实施方式包括公式I-P、I-O或I-M的化合物，通过该化合物保护有机材料的过程，使用该化合物对抗有机材料的降解，包括该化合物的添加剂组成，制造该化合物的过程以及其中所涉及的中间体。
• Can carrier composition
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0310092A2

  公开（公告）日：1989-04-05

  A can carrier composition comprising at least one of each of the following components wherein all parts are by weight based on 100 parts by weight of component (i): (i) a high pressure polyethylene having a density in the range of about 0.918 to about 0.930 gram per cubic centimeter; (ii) a linear polyethylene having a density of less than about 0.925 gram per cubic centimeter in an amount of about 2 to about 35 parts; (iii) polyethylene wax in an amount of about 0.5 to about 5 parts; (iv) a mineral filler coated with a metal salt of a fatty acid in an amount of about 0.05 to about 0.50 parts; (v) a secondary amide in an amount of about 0.02 to about 0.15 part; (vi) an antioxidant in an amount of about 0.02 to about 0.10 part; and (vii) an organic phosphorus compound in an amount of about 0.005 to about 0.05 part.

  一种易拉罐载体组合物，包含以下每种成分中的至少一种，其中所有成分的重量均以 100 份成分(i)的重量为基准： (i) 密度在每立方厘米约 0.918 至约 0.930 克范围内的高压聚乙烯； (ii) 密度小于每立方厘米约 0.925 克的线性聚乙烯，其用量为约 2 至约 35 份； (iii) 聚乙烯蜡，用量约为 0.5 至约 5 份； (iv) 塗有脂肪酸的金屬鹽的礦物填料，份量約為 0.05 至約 0.50 份； (v) 一种仲酰胺，用量约为 0.02 至约 0.15 份 (vi) 抗氧化剂，用量约为 0.02 至约 0.10 份；以及 (vii) 有机磷化合物，用量约为 0.005 至约 0.05 份。
• Resin compositions
  申请人：NIPPON PETROCHEMICALS COMPANY, LIMITED

  公开号：EP0430598A2

  公开（公告）日：1991-06-05

  Resin compositions are made up essentially of a selected class of random copolymers and a selected class of hydrogen donors. The random copolymer results from an ethylene monomer and a styrene-based monomer, whereas the hydrogen donor is chosen from one or more hyrogenated oils of a petroleum or coal origin fractionated to boil in a specified range of temperatures. Radiation resistance is greatly enhanced. Also incorporated in the composition is a selected class of flame retardants to improve resistance to flammability.

  树脂组合物主要由一类选定的无规共聚物和一类选定的氢供体组成。无规共聚物由乙烯单体和苯乙烯基单体组成，而氢供体则选自一种或多种石油或煤炭来源的氢化油，经分馏后可在指定温度范围内沸腾。耐辐射性大大增强。该组合物中还加入了一类选定的阻燃剂，以提高耐燃性。
• Polyester molding for use with a casing
  申请人：SONY CORPORATION

  公开号：EP1275690A2

  公开（公告）日：2003-01-15

  By molding a biodegradable plastic material which is treated with a compound reactive to the active hydrogen in the biodegradable plastic material, a biodegradable plastic material and molding having long-term reliability are obtained.

  通过使用与生物可降解塑料材料中的活性氢反应的化合物处理生物可降解塑料材料，可获得具有长期可靠性的生物可降解塑料材料和模塑件。